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Melt-Polymerization of TEMPO Methacrylates with Nano Carbons Enables Superior Battery Materials

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Vlad, Alexandru [UCL] Rolland, Julien Hauffman, Guillaume Ernould, Bruno Gohy, Jean-François [UCL]

A solvent-free, melt polymerization process of a 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) precursor for rechargeable organic radical batteries is proposed. In situ carbon incorporation in the melted monomer phase yields a nanoscale homogenous polymer composite. Superior battery performances including higher power and cycling stability are attained by using the melt-polymerization method.

Document type Article de périodique (Journal article) – Article de recherche
Publication date 2015
Language Anglais
Journal information "ChemSusChem (Print) : chemistry & sustainability, energy & materials" - Vol. 8, no.10, p. 1692-1696 (2015)
Peer reviewed yes
Publisher Wiley - V C H Verlag GmbH & Co. KGaA (Weinheim)
issn 1864-5631
Publication status Publié
Affiliation UCL - SST/IMCN/BSMA - Bio and soft matter
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Bibliographic reference Vlad, Alexandru ; Rolland, Julien ; Hauffman, Guillaume ; Ernould, Bruno ; Gohy, Jean-François. Melt-Polymerization of TEMPO Methacrylates with Nano Carbons Enables Superior Battery Materials. In: ChemSusChem (Print) : chemistry & sustainability, energy & materials, Vol. 8, no.10, p. 1692-1696 (2015)
Permanent URL http://hdl.handle.net/2078.1/162263