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Si-29 nuclear magnetic resonance of poly(methylphenyl)silane

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Demahieu, AF. Devaux, Jacques [UCL] Dereppe, C. Baudoux, G Delhalle, Joseph [FUNDP]

A Cl-terminated poly(methylphenyl)silane is synthesized and analyzed by Si-29-NMR spectroscopy. Assignments are proposed for the different peaks observed. A modification of the chemical shifts of the peaks relative to the main chain atoms is observed upon heating. From these experimental results and computational calculations on model compounds, the assignments of the three main peaks to configurationally different Si atoms are confirmed. (C) 1996 John Wiley & Sons, Inc.

Document type Article de périodique (Journal article) – Article de recherche
Publication date 1996
Language Anglais
Journal information "Journal of Polymer Science. Part A, Polymer Chemistry" - Vol. 34, no. 5, p. 763-769 (1996)
Peer reviewed yes
Publisher John Wiley & Sons Inc (New York)
issn 0887-624X
e-issn 1099-0518
Publication status Publié
Affiliation UCL
Keywords poly(methylphenyl)silane ; Si-29-NMR ; computational calculations
Links
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Bibliographic reference Demahieu, AF. ; Devaux, Jacques ; Dereppe, C. ; Baudoux, G ; Delhalle, Joseph. Si-29 nuclear magnetic resonance of poly(methylphenyl)silane. In: Journal of Polymer Science. Part A, Polymer Chemistry, Vol. 34, no. 5, p. 763-769 (1996)
Permanent URL http://hdl.handle.net/2078.1/47593