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Proof of the Stereochemistry of Cis-2,5-dibromocyclopentanone

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Boelens, M. Declercq, Jean-Paul [UCL] Dekimpe, N. Keppens, M.

The assignment of the long-standing problem of the stereochemistry of cis-2,5-dibromocyclopentanone has been performed by stereoselective reduction into cis, cis-2,5-dibromocyclopentanol, conversion of the latter alcohol into the 4-nitrobenzoate ester, and following H-1 NMR and X-ray crystallographic-analysis.

Document type Article de périodique (Journal article) – Article de recherche
Publication date 1994
Language Anglais
Journal information "The Journal of Organic Chemistry" - Vol. 59, no. 15, p. 4170-4171 (1994)
Peer reviewed yes
Publisher Amer Chemical Soc (Washington)
issn 0022-3263
e-issn 1520-6904
Publication status Publié
Affiliation UCL
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Bibliographic reference Boelens, M. ; Declercq, Jean-Paul ; Dekimpe, N. ; Keppens, M.. Proof of the Stereochemistry of Cis-2,5-dibromocyclopentanone. In: The Journal of Organic Chemistry, Vol. 59, no. 15, p. 4170-4171 (1994)
Permanent URL http://hdl.handle.net/2078.1/48801