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Chiral properties of tetrathiatriarylmethyl spin probes

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Driesschaert, Benoît [UCL] Robiette, Raphaël [UCL] Lucaccioni, Fabio [UCL] Gallez, Bernard [UCL] Marchand-Brynaert, Jacqueline [UCL]

We report that tetrathiatriarylmethyl (trityl) EPR probes are chiral molecules at room temperature, the two stereoisomers that differ in their helicity being configurationally stable enough to be separated and stored independently.

Document type Article de périodique (Journal article) – Article de recherche
Access type Accès restreint
Publication date 2011
Language Anglais
Journal information "Chemical communications" - Vol. 47, no. 16, p. 4793-4795 (2011)
Peer reviewed yes
Publisher Royal Society of Chemistry
issn 1359-7345
Publication status Publié
Affiliations UCL - SST/IMCN/MOST - Molecules, Solids and Reactivity
UCL - SSS/LDRI - Louvain Drug Research Institute
UCL - (SLuc) Service de médecine nucléaire
Keywords Intracellular ocygen probes ; Biomedical epr applications ; Persistent trityl radicals ; Sensitivity ; Ph ; CECI ; CISM
Links
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Bibliographic reference Driesschaert, Benoît ; Robiette, Raphaël ; Lucaccioni, Fabio ; Gallez, Bernard ; Marchand-Brynaert, Jacqueline. Chiral properties of tetrathiatriarylmethyl spin probes. In: Chemical communications, Vol. 47, no. 16, p. 4793-4795 (2011)
Permanent URL http://hdl.handle.net/2078.1/76445