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Design and Synthesis of New Octupolar Molecules for Second-Harmonic Generation

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Bluet, Guillaume [] Brasselet, Sophie [] Druzé, Nadine [] Ledoux, Isabelle [UCL] Lefloch, Fabrice [] Riant, Olivier [UCL]

The state of the art concerning the design of octupoles, a new familly of NLO active molecules is presented here. 2D and 3D based architectures with higher symmetries lead to high efficiencies for SHG.

Document type Article de périodique (Journal article)
Publication date 1998
Language Anglais
Journal information "Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals" - Vol. 322, no. 1, p. 35-42 (1998)
Publisher Taylor & Francis Inc. (Philadelphia)
issn 1058-725X
Publication status Publié
Affiliation Université Paris-Sud (France) - Chimie organique
Links
  1. Zyss J., Nonlinear Optical properties of Organic Molecules and Crystals (1987)
  2. Blanchard-Desce M., Alain V., Bedworth P. V., Marder S. R., Fort A., Runser C., Barzoukas M., Lebus S., Wortmann R., Large Quadratic Hyperpolarizabilities with Donor–Acceptor Polyenes Exhibiting Optimum Bond Length Alternation: Correlation Between Structure and Hyperpolarizability, 10.1002/chem.19970030717
  3. Ledoux I., Zyss J., Siegel J.S., Brienne J., Lehn J.-M., Second-harmonic generation from non-dipolar non-centrosymmetric aromatic charge-transfer molecules, 10.1016/0009-2614(90)80135-z
  4. Voigt-Martin Ingrid G., Li Gao, Yakimanski A., Schulz Gabriela, Wolff J. Jens, The Origin of Nonlinear Optical Activity of 1,3,5-Triamino-2,4,6-trinitrobenzene in the Solid State:  The Crystal Structure of a Non-Centrosymmetric Polymorph as Determined by Electron Diffraction, 10.1021/ja9611708
  5. Joffre Manuel, Yaron David, Silbey Robert J., Zyss Joseph, Second order optical nonlinearity in octupolar aromatic systems, 10.1063/1.463768
  6. Thalladi Venkat R., Brasselet Sophie, Weiss Hans-Christoph, Bläser Dieter, Katz Amy K., Carrell H. L., Boese Roland, Zyss Joseph, Nangia Ashwini, Desiraju Gautam R., Crystal Engineering of Some 2,4,6-Triaryloxy-1,3,5-triazines:  Octupolar Nonlinear Materials, 10.1021/ja972830r
  7. Terhune R. W., Maker P. D., Savage C. M., Measurements of Nonlinear Light Scattering, 10.1103/physrevlett.14.681
  8. Maker P. D., Spectral Broadening of Elastic Second-Harmonic Light Scattering in Liquids, 10.1103/physreva.1.923
  9. Clays Koen, Persoons André, Hyper-Rayleigh scattering in solution, 10.1103/physrevlett.66.2980
  10. Zyss Joseph, Dhenaut Christophe, Chauvan Thai, Ledoux Isabelle, Quadratic nonlinear susceptibility of octupolar chiral ions, 10.1016/0009-2614(93)85574-8
  11. Morrison I. D., Denning R. G., Laidlaw W. M., Stammers M. A., Measurement of first hyperpolarizabilities by hyper‐Rayleigh scattering, 10.1063/1.1146871
  12. Zyss Joseph, Ledoux Isabelle, Nonlinear optics in multipolar media: theory and experiments, 10.1021/cr00025a003
  13. Verbiest T., Clays K., Samyn C., Wolff J., Reinhoudt D., Persoons A., Investigations of the Hyperpolarizability in Organic Molecules from Dipolar to Octopolar Systems, 10.1021/ja00099a058
  14. Ray Paresh Chandra, Das Puspendu Kumar, First-order hyperpolarizabilities of octupolar aromatic molecules: symmetrically substituted triazines, 10.1016/0009-2614(95)00913-o
  15. Wortmann Rüdiger, Glania Christoph, Krämer Peter, Matschiner Ralf, Jens Wolff J., Kraft Stefan, Treptow Björn, Barbu Eugen, Längle Daniela, Görlitz Gunter, Nondipolar Structures With Threefold Symmetry For Nonlinear Optics, 10.1002/chem.19970031107
  16. Stadler S., Feiner F., Bräuchle Ch., Brandl S., Gompper R., Determination of the first hyperpolarizability of four octupolar molecules and their dipolar subunits via hyper-Rayleigh scattering in solution, 10.1016/0009-2614(95)01005-t
  17. Whittall Ian R., Humphrey Mark G., Houbrechts Stephan, Maes Joachim, Persoons André, Schmid Siegbert, Hockless David C.R., Organometallic complexes for nonlinear optics. 14. Syntheses and second-order nonlinear optical properties of ruthenium, nickel and gold σ-acetylides of 1,3,5-triethynylbenzene: X-ray crystal structures of 1-(HC≡C)-3,5-C6H3(trans-C≡CRuCl(dppm)2)2 and 1,3,5-C6H3(C≡CAu(PPh3))3, 10.1016/s0022-328x(97)00320-3
  18. Sastre A., Torres T., Díaz-García M. A., Agulló-López F., Dhenaut C., Brasselet S., Ledoux I., Zyss J., Subphthalocyanines:  Novel Targets for Remarkable Second-Order Optical Nonlinearities, 10.1021/ja9533050
  19. Zyss Joseph, Van Thai Chau, Dhenaut Christophe, Ledoux Isabelle, Harmonic rayleigh scattering from nonlinear octupolar molecular media: the case of crystal violet, 10.1016/0301-0104(93)80196-g
  20. Verbiest T., Meyers F., Brédas J. L., Clays K., Persoons A., Determination of the hyperpolarizability of an octopolar molecular ion by hyper-Rayleigh scattering, 10.1364/ol.18.000525
  21. Luo Yi, Cesar Amary, Ågren Hans, The hyperpolarizability of the tricyanomethanide molecular ion in solution, 10.1016/0009-2614(96)00167-4
  22. Blanchard-Desce Mireille, Baudin Jean-Bernard, Ruel Odile, Jullien Ludovic, Brasselet Sophie, Zyss Joseph, New non-dipolar structures with significant quadratic hyperpoiarizabilites, 10.1016/s0925-3467(97)00119-5
  23. Lambert Christoph, Schmälzlin Elmar, Meerholz Klaus, Bräuchle Christoph, Synthesis and Nonlinear Optical Properties of Three-Dimensional Phosphonium Ion Chromophores, 10.1002/(sici)1521-3765(19980310)4:3<512::aid-chem512>3.0.co;2-7
  24. Dhenaut Christophe, Ledoux Isabella, Samuel Ifor D. W., Zyss Joseph, Bourgault Manuel, Bozec Hubert Le, Chiral metal complexes with large octupolar optical nonlinearities, 10.1038/374339a0
  25. Lequan Minh, Branger Catherine, Simon Jacques, Thami Thierry, Chauchard Eve, Persoons Andr�, First hyperpolarizability of organotin compounds withTd symmetry, 10.1002/adma.19940061110
  26. Riant Olivier, Samuel Odile, Kagan Henri B., A general asymmetric synthesis of ferrocenes with planar chirality, 10.1021/ja00066a066
  27. Riant Olivier, Samuel Odile, Flessner Timo, Taudien Stephan, Kagan Henri B., An Efficient Asymmetric Synthesis of 2-Substituted Ferrocenecarboxaldehydes, 10.1021/jo970075u
  28. Nunzi Jean-Michel, Charra Fabrice, Fiorini Céline, Zyss Joseph, Transient optically induced non-centrosymmetry in a solution of octupolar molecules, 10.1016/0009-2614(94)00099-9
  29. Fiorini Céline, Samuel Ifor D. W., Zyss Joseph, Charra Fabrice, Nunzi Jean-Michel, Light-induced second-harmonic generation in an octupolar dye, 10.1364/ol.20.002469
Bibliographic reference Bluet, Guillaume ; Brasselet, Sophie ; Druzé, Nadine ; Ledoux, Isabelle ; Lefloch, Fabrice ; et. al. Design and Synthesis of New Octupolar Molecules for Second-Harmonic Generation. In: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol. 322, no. 1, p. 35-42 (1998)
Permanent URL http://hdl.handle.net/2078.1/94837