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Nickel(II) Phosphane‐ and N‐heterocyclic Carbene Complexes with Tridentate, Dianionic [S,N,O]2– Ligands

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Rust,  Jörg
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Lehmann,  Christian W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Koch, L., Rust, J., Lehmann, C. W., & Mohr, F. (2020). Nickel(II) Phosphane‐ and N‐heterocyclic Carbene Complexes with Tridentate, Dianionic [S,N,O]2– Ligands. Zeitschrift für anorganische und allgemeine Chemie, 646(10), 469-474. doi:10.1002/zaac.202000130.


Cite as: https://hdl.handle.net/21.11116/0000-0007-2EBE-1
Abstract
Square‐planar dinuclear nickel(II) complexes containing [S,N,O]2– ligands formed by condensation of acetyl acetone or benzoyl acetone with cysteamine were prepared. These dimeric nickel(II) compounds undergo bridge‐cleavage reactions with the cage phosphine PTA (PTA = 1,3,5‐triaza‐7‐phosphaadamantane) or in situ generated N‐heterocyclic carbenes. The resulting diamagnetic, square planar NiII complexes were characterized by spectroscopic methods and X‐ray diffraction.