Controlled lignosulfonate depolymerization via solvothermal fragmentation 
coupled with catalytic hydrogenolysis/hydrogenation in continuous flow reactor

Brandi, Francesco; Antonietti, Markus; Al-Naji, Majd

doi:10.1039/D1GC01714D

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Controlled lignosulfonate depolymerization via solvothermal fragmentation coupled with catalytic hydrogenolysis/hydrogenation in continuous flow reactor

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Brandi, Francesco
Majd Al-Naji, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Antonietti, Markus
Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Al-Naji, Majd
Majd Al-Naji, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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引用

Brandi, F., Antonietti, M., & Al-Naji, M. (2021). Controlled lignosulfonate depolymerization via solvothermal fragmentation coupled with catalytic hydrogenolysis/hydrogenation in continuous flow reactor. Green Chemistry, 23(24), 9894-9905. doi:10.1039/D1GC01714D.

引用: https://hdl.handle.net/21.11116/0000-0009-2D18-B

要旨

Sodium lignosulfonate (LS) was valorized to low molecular weight (Mw) fractions by combining solvothermal (SF) and catalytic hydrogenolysis/hydrogenation fragmentation (SHF) in continuous flow system. This achieved in either alcohol/water (EtOH₂O or MeOH/H₂O) as a solvent and Ni on nitrogen-doped carbon as a catalyst. The tunability according to temperature of both SF and catalytic SHF of LS has been separately investigated at 150°C, 200°C and 250°C. In SF, the minimal Mw was 2994 g mol^-1 at 250°C with a dispersity (Đ) of 5.3 using MeOH/H₂O. In catalytic SHF using MeOH/water, extremely low Mw was found (433 mg gLS^-1) with Đ of 1.2 combined with 34 mg gLS^-1. The monomer yield was improved to 42 mg gLS^-1 using dual catalytic beds. These results is a direct evident that lignin is an unstable polymer at elevated temperature and could be efficiently deconstructed in hydrothermal conditions with and without catalyst.