Journal Article FZJ-2018-04249

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Dependence of the adsorption height of graphenelike adsorbates on their dimensionality

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2018
Inst. Woodbury, NY

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Abstract: Comparing the adsorption heights of various graphene nanoribbons on Cu(111) and Au(111) surfaces to those of graphene and π-conjugated planar organic molecules, we observe that two-dimensional graphene adsorbs much further away from the surface than both one-dimensional graphene nanoribbons and π-conjugated planar molecules -- which represent zero-dimensional graphene flakes. We show that this is a direct consequence of the adsorbates' dimensionality. Our results provide invaluable insights into the interplay of Pauli repulsion, pushback effect and chemical interaction for graphene-like adsorbates of any dimensionality on metal surfaces.

Classification:

Contributing Institute(s):
  1. Quantum Nanoscience (PGI-3)
Research Program(s):
  1. 143 - Controlling Configuration-Based Phenomena (POF3-143) (POF3-143)
  2. DFG project 396769409 - Grundlagen der Photoemissionstomographie (396769409)

Appears in the scientific report 2018
Database coverage:
Medline ; American Physical Society Transfer of Copyright Agreement ; OpenAccess ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; IF < 5 ; JCR ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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 Record created 2018-07-17, last modified 2023-08-15