Journal Article FZJ-2015-04121

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Enthalpies of Formation of (Cu,Ni)$_{3}$Sn, (Cu,Ni)$_{6}$Sn$_{5}$-HT and (Ni,Cu)$_{3}$Sn$_{2}$-HT

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2014
Springer Boston, Mass.

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Abstract: Standard enthalpies of formation of ternary phases in the Cu-Ni-Sn system were determined along sections at 25, 41 and 45.5 at.% Sn applying tin solution drop calorimetry. Generally, the interaction of Ni with Sn is much stronger than that of Cu with Sn. Along all sections the enthalpy of formation changes almost linearly with the mutual substitution of Cu and Ni within the respective homogeneity ranges. Thus no additional ternary interaction promoting the formation of further Cu-Ni-Sn phases can be assumed. The results are discussed and compared with literature values relevant to this system.

Classification:

Contributing Institute(s):
  1. Werkstoffstruktur und -eigenschaften (IEK-2)
Research Program(s):
  1. 122 - Power Plants (POF2-122) (POF2-122)

Appears in the scientific report 2015
Database coverage:
OpenAccess ; Current Contents - Physical, Chemical and Earth Sciences ; IF < 5 ; JCR ; SCOPUS ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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Open Access

 Record created 2015-06-12, last modified 2021-01-29