Vibrational states at the dissociation limit protected from vibrational energy flow

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https://hdl.handle.net/2142/55878

Title: Vibrational states at the dissociation limit protected from vibrational energy flow
Author(s): Gruebele, Martin
Issue Date: 2014-06-16
Keyword(s): Mini-symposium: Spectroscopy in Kinetics and Dynamics
Abstract: I will discuss the detection of sharp vibrational transitions with up to 40 quanta of total excitation above the dissociation limit of thiophosgene (SCCl$_2$). A 6-D CASSCF calculation and filtered diagonalization of eigenstates to compute dilution factors for bright states explains the 'survival' of these states and their expected number quantitatively.
Publisher: International Symposium on Molecular Spectroscopy
Type of Resource: text
Language: en
Permalink: http://hdl.handle.net/2142/55878
DOI: https://doi.org/10.15278/isms.2014.MH07
Copyright and License Information: Copyright 2014 by the authors. Licensed under a Creative Commons Attribution 4.0 International License. http://creativecommons.org/licenses/by/4.0/