University of Illinois Urbana-Champaign

Synthesis and Characterization of Organometallic Cyanides and Phthalocyanines

Contakes, Stephen Myron

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Description

Title
Synthesis and Characterization of Organometallic Cyanides and Phthalocyanines
Author(s)
Contakes, Stephen Myron
Issue Date
2001
Doctoral Committee Chair(s)
Rauchfuss, Thomas B.
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Chemistry, Inorganic
Language
eng
Abstract
pi-arene complexes of octaalkoxyphthalocyanines and metallophthalocyanines were prepared by reaction of soluble phthalocyanine (H2PcOR) and metallophthalocyanine (M(PcOR)) ligands with Cp*Ru(NCMe)3 +. The molecular structure of {Cp*Ru[eta6-Ni(PcOBu)]}PF 6 consists of a dimer of two cofacially stacked {Cp*Ru[eta 6-Ni(PcOBu)]}+ units. In [Cp*Ru(eta6-H 2PcOEt)]PF6 the two NH protons exhibit differences in reactivity, and the N4H2 pocket can be metallated.
Graduation Semester
2001
Type of Resource
text
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http://hdl.handle.net/2142/84034

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