The adsorption of 4-nitroanisole on silver colloidal nanoparticles was investigated by surface-enhanced Raman spectroscopy (SERS). Actually, the chemical binding with a metal substrate may play a role in changing the electronic structure of this molecule, which can be considered a push–pull chromophore, because an internal charge-transfer occurs between methoxy and nitrogroup. A SERS signal could be detected only in chloride-activated silver colloids, but the spectrum recorded with green-light excitation was not related to adsorbed 4-nitroanisole, but to its azoderivative, formed by photoreduction of the nitrogroup on the surface of the silver substrate.
SERS investigation on the adsorption and photoreaction of 4-nitroanisole in Ag hydrosols / Maurizio Muniz-Miranda. - In: JOURNAL OF RAMAN SPECTROSCOPY. - ISSN 0377-0486. - STAMPA. - 44:(2013), pp. 1416-1421. [10.1002/jrs.4236]
SERS investigation on the adsorption and photoreaction of 4-nitroanisole in Ag hydrosols
MUNIZ-MIRANDA, MAURIZIO
2013
Abstract
The adsorption of 4-nitroanisole on silver colloidal nanoparticles was investigated by surface-enhanced Raman spectroscopy (SERS). Actually, the chemical binding with a metal substrate may play a role in changing the electronic structure of this molecule, which can be considered a push–pull chromophore, because an internal charge-transfer occurs between methoxy and nitrogroup. A SERS signal could be detected only in chloride-activated silver colloids, but the spectrum recorded with green-light excitation was not related to adsorbed 4-nitroanisole, but to its azoderivative, formed by photoreduction of the nitrogroup on the surface of the silver substrate.File | Dimensione | Formato | |
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