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Total Synthesis of (−)-Daphenylline
http://hdl.handle.net/2237/25060
http://hdl.handle.net/2237/250602c7c0148-b903-4f38-b8df-9f074d13be1e
名前 / ファイル | ライセンス | アクション |
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20160318_daphenylline.pdf ファイル公開:2017-05-10 (1.0 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2016-11-18 | |||||
タイトル | ||||||
タイトル | Total Synthesis of (−)-Daphenylline | |||||
言語 | en | |||||
著者 |
Yamada, Ryosuke
× Yamada, Ryosuke× Adachi, Yohei× Yokoshima, Satoshi× Fukuyama, Tohru |
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アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
権利 | ||||||
言語 | en | |||||
権利情報 | This is the peer reviewed version of the following article: [ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. v.55, n.20, 2016, p.6067-6070], which has been published in final form at [http://doi.org/10.1002/anie.201601958]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. | |||||
抄録 | ||||||
内容記述 | Total synthesis of (−)-daphenylline, a hexacyclic Daphniphyllum alkaloid, was achieved. Construction of the tricyclic DEF ring system was initiated by asymmetric Negishi coupling followed by an intramolecular Friedel–Crafts reaction. Installation of a side chain onto the tricyclic core was carried out through Sonogashira coupling, stereocontrolled Claisen rearrangement by taking advantage of the characteristic conformation of the tricyclic DEF core, and the stereoselective alkylation of a lactone. After the introduction of a glycine unit, the ABC ring system was stereoselectively constructed through intramolecular cycloaddition of the cyclic azomethine ylide. | |||||
言語 | en | |||||
内容記述タイプ | Abstract | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | Wiley | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプresource | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1002/anie.201601958 | |||||
ISSN | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 1433-7851 | |||||
書誌情報 |
en : ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 巻 55, 号 20, p. 6067-6070, 発行日 2016-05-10 |
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著者版フラグ | ||||||
値 | author | |||||
URI | ||||||
識別子 | http://doi.org/10.1002/anie.201601958 | |||||
識別子タイプ | DOI | |||||
URI | ||||||
識別子 | http://hdl.handle.net/2237/25060 | |||||
識別子タイプ | HDL |