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不活性C-H結合に対する新攻撃法とそのエンメインよりジベレリンA15合成への応用: ダイテルペノイドの化学的研究(第1報)
http://hdl.handle.net/2297/43973
http://hdl.handle.net/2297/43973546ac37d-9329-4cce-b766-1e06082f5e2a
名前 / ファイル | ライセンス | アクション |
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PH-PR-SOMEI-M-397.pdf (1.5 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2017-10-04 | |||||
タイトル | ||||||
タイトル | 不活性C-H結合に対する新攻撃法とそのエンメインよりジベレリンA15合成への応用: ダイテルペノイドの化学的研究(第1報) | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | A Novel Method for Functionalization of Non-Activated C-H Bond and Its Application to the Synthesis of Gibberellin A15: Chemical Studies on Diterpenoids. I | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
染井, 正徳
× 染井, 正徳× 岡本, 敏彦 |
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書誌情報 |
藥學雜誌 = Journal of the Pharmaceutical Society of Japan 巻 92, 号 4, p. 397-410, 発行日 1972-01-01 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0031-6903 | |||||
NCID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00284903 | |||||
出版者 | ||||||
出版者 | 日本薬学会 = Pharmaceutical Society of Japan | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | On the assumption that non-activated C-H bond should be functionalized by the photolysis of some nitrones, the nitrone [24] derived from Enmein [1] in 14 steps was photodecomposed under various conditions, and the expected products [25 and 26] were obtained in a favorable yield. The structure of the compound [25] was determined unequivocally, and the possible mechanisms (d and e) (Fig. 4) were presumed. The compound [25] was then converted into gibberellin A15 in 6 steps. The route of [41]→[43]+[44] seems to be interesting, suggesting the biogenesis of gibberellin from kaurene. | |||||
権利 | ||||||
権利情報 | Copyright © PHARMACEUTICAL SOCIETY OF JAPAN | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | http://www.pharm.or.jp/ | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://www.jstage.jst.go.jp/browse/yakushi/-char/ja/ |