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Crystal structure of (aceto-nitrile-κN)iodido-(2-(naphthalen-1-yl)-6-{1-[(2,4,6-tri-methyl-phen-yl)imino]ethyl}-pyridine-κ(2)N,N')copper(I).
journal contribution
posted on 2017-01-04, 14:42 authored by Nada Al-Najjar, Gregory A. Solan, Kuldip SinghIn the mononuclear title complex, [CuI(C2H3N)(C26H24N2)], the Cu(I) ion has a distorted tetra-hedral coordination environment, defined by two N atoms of the chelating 2-(naphthalen-1-yl)-6-[(2,4,6-tri-methyl-phen-yl)imino]-pyridine ligand, one N atom of an aceto-nitrile ligand and one iodide ligand. Within the complex, there are weak intra-molecular C-H⋯N hydrogen bonds, while weak inter-molecular C-H⋯I inter-actions between complex mol-ecules, help to facilitate a three-dimensional network.
History
Citation
Acta Crystallographica Section E: Crystallographic Communications, 2016, 72 (Pt 12), pp. 1845-1847Author affiliation
/Organisation/COLLEGE OF SCIENCE AND ENGINEERING/Department of ChemistryVersion
- VoR (Version of Record)