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タイトル: Formation of Bi,Pb-2223 and microstructural evolution in Pb-Ca-Cu deposited Bi-2212(001) single crystal by heat treatment
著者: Kajihara, T.
Shimada, Y.
Hata, S.
Ikeda, K.
Nakashima, H.
Matsumoto, A.
Mochiku, T.
Kitaguchi, H.
Doi, T.
著者名の別形: 土井, 俊哉
キーワード: Bi, Pb-2223
Bi-2212 single crystal
Pb-Ca-Cu film
Phase transformation
Heat treatment
Scanning electron microscopy
Scanning transmission electron maicroscopy
発行日: 2013
出版者: Elsevier B.V.
誌名: Physics Procedia
巻: 45
開始ページ: 69
終了ページ: 72
抄録: In order to study the mechanism of phase transformation from Bi-2212 to Bi-2223, we fabricated Pb-Ca-Cu deposited Bi-2212 (001) single crystals as precursors of the Bi, Pb-2223 phase. These single crystals were heated in a sintered Bi-Pb-Sr-Ca-Cu-O pellet, and microstructure was observed by analytical electron microscopy. As a result of the microstructural observation around the Bi, Pb-2223 phase, two formation paths of Bi, Pb-2223 were recognized. One is the formation from a liquid phase which is formed by Bi-2212 and melting of the secondary phases such as (Ca, Sr)2PbO4 and CuO. The other is the growth of Bi, Pb-2223 into Bi-2212 phase by diffusion of Pb, Ca and Cu atoms along the 〈hk0〉 directions of Bi-2212.
記述: 25th International Symposium on Superconductivity, ISS 2012 ; 3 December 2012 through 5 December 2012 ; Tokyo
著作権等: © 2013 The Authors. Published by Elsevier B.V. Open access under CC BY-NC-ND license.
URI: http://hdl.handle.net/2433/235666
DOI(出版社版): 10.1016/j.phpro.2013.04.054
出現コレクション:学術雑誌掲載論文等

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