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2213337203666160525102910.pdf | 1.08 MB | Adobe PDF | 見る/開く |
タイトル: | Review of Reactions and Molecular Mechanisms in Cellulose Pyrolysis |
著者: | Kawamoto, Haruo https://orcid.org/0000-0002-4934-8054 (unconfirmed) |
著者名の別形: | 河本, 晴雄 |
キーワード: | Cellulose pyrolysis gasification carbonization molecular mechanism controlled pyrolysis hydrogen bond theory |
発行日: | 25-May-2016 |
出版者: | Bentham Science Publishers Ltd. |
誌名: | Current Organic Chemistry |
巻: | 20 |
号: | 23 |
開始ページ: | 2444 |
終了ページ: | 2457 |
抄録: | Cellulose, which is a polymer of β-1→4 linked D-glucose units, comprises about half the components of lignocellulosic biomasses. A better understanding of the chemistry involved in cellulose pyrolysis provides valuable insights into the development of efficient pyrolysis-based conversion technologies of biomass into biofuels, biochemicals and biomaterials. This review focuses on the reactions and molecular mechanisms that determine the reactivity and product selectivity in pyrolysis and the related conversion technologies. This information is useful for understanding the processing technologies conducted at high temperatures, such as wood drying and the production of cellulose-plastic composite materials. Because the cellulose pyrolysis behavior changes drastically in the temperature range of 300–350 °C, this review is divided into low- and high-temperature regimes. The intermediates produced from cellulose pyrolysis are further converted into various gas, liquid or solid products. Hence, these processes are addressed as primary pyrolysis and secondary reactions in this review. The roles of the crystalline cellulose in pyrolysis are noted. |
著作権等: | This is the ACCEPTED VERSION of the peer-reviewed article. The published manuscript is available at EurekaSelect via http://www.eurekaselect.com/142480 The full-text file will be made open to the public on 25 May 2017 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 |
URI: | http://hdl.handle.net/2433/240620 |
DOI(出版社版): | 10.2174/2213337203666160525102910 |
出現コレクション: | 学術雑誌掲載論文等 |
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