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j.carbon.2018.06.004.pdf | 1.04 MB | Adobe PDF | 見る/開く |
タイトル: | ¹³C/¹⁹F high-resolution solid-state NMR studies on layered carbon-fluorine compounds |
著者: | Murakami, Miwa https://orcid.org/0000-0001-6209-4450 (unconfirmed) Matsumoto, Kazuhiko https://orcid.org/0000-0002-0770-9210 (unconfirmed) Hagiwara, Rika https://orcid.org/0000-0002-7234-3980 (unconfirmed) Matsuo, Yoshiaki |
著者名の別形: | 村上, 美和 松本, 一彦 萩原, 理加 |
発行日: | Nov-2018 |
出版者: | Elsevier BV |
誌名: | Carbon |
巻: | 138 |
開始ページ: | 179 |
終了ページ: | 187 |
抄録: | ¹³C/¹⁹F high-resolution solid-state NMR was applied to examine local structures of a stage-1 layered carbon-fluorine compound (C₂.₈). Four ¹⁹F(F1∼F4) and two ¹³C signals (C1 and C2) unraveled by high magnetic field (14 T) and fast magic-angle spinning (>35 kHz) were examined by various two-dimensional correlation experiments. In addition to “through space” ¹³C-¹⁹F and ¹⁹F-¹⁹F dipolar correlation, which reveals distance proximity among ¹³C/¹⁹F spins, we examined feasibility of applying the J interaction for examination of “through bond” correlation. These experiments led assignment of two of the four F signals (F2 and F3) to F directly covalent bonded to sp³ carbon and an interleaving domain for the local structure of the minor C2-F3 group among the major domain composed of C2-F2 and sp² carbon (C1). The other two ¹⁹F signals (F1 and F4) were assigned to as CF₂ and F ions, respectively. A spectroscopic evidence for the C-F bond being the σ bond is given by the observation of a non-zero one-bond J value (193 ± 4 Hz) for C2-F. Further, the similar JCF = 197 Hz for C-F in poly(carbon fluoride) confirmed that the so-called “semi-ionic/semi-covalent” C-F bond in C₂.₈F is actually a “standard” covalent C-F bond. |
著作権等: | © 2018. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/. The full-text file will be made open to the public on 1 November 2020 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。 This is not the published version. Please cite only the published version. |
URI: | http://hdl.handle.net/2433/245143 |
DOI(出版社版): | 10.1016/j.carbon.2018.06.004 |
出現コレクション: | 学術雑誌掲載論文等 |
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