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https://hdl.handle.net/2440/131499
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Type: | Journal article |
Title: | Significantly raised visible-light photocatalytic H₂ evolution on a 2D/2D ReS₂/In₂ZnS₄ van der Waals heterostructure |
Other Titles: | Significantly raised visible-light photocatalytic H(2) evolution on a 2D/2D ReS(2)/In(2)ZnS(4) van der Waals heterostructure |
Author: | Ran, J. Zhang, H. Qu, J. Shan, J. Davey, K. Cairney, J.M. Jing, L. Qiao, S. |
Citation: | Small, 2021; 17(32):2100296-1-2100296-8 |
Publisher: | Wiley |
Issue Date: | 2021 |
ISSN: | 1613-6829 1613-6829 |
Statement of Responsibility: | Jingrun Ran, Hongping Zhang, Jiangtao Qu, Jieqiong Shan, Kenneth Davey, Julie M. Cairney, Liqiang Jing, and Shi-Zhang Qiao |
Abstract: | Owing to dwindling fossil fuels reserves, the development of alternative renewable energy sources is globally important. Photocatalytic hydrogen (H₂) evolution represents a practical and affordable alternative to convert sunlight into carbon-free H₂ fuel. Recently, 2D/2D van der Waals heterostructures (vdWHs) have attracted significant research attention for photocatalysis. Here, for the first time a ReS₂/In₂ZnS₄ 2D/2D vdWH synthesized via a facile physical mixing is reported. It exhibits a highly promoted photocatalytic H₂ -evolution rate of 2515 µmol h⁻¹ g⁻¹. Importantly, this exceeds that for pristine In₂ZnS₄ by about 22.66 times. This, therefore, makes ReS₂/In₂ZnS₄ one of the most efficient In₂ZnS₄ -based photocatalysts without noble-metal cocatalysts. Advanced characterizations and theoretical computations results show that interlayer electronic interaction within ReS₂/In₂ZnS₄ vdWH and atomic-level S active centers along the edges of ReS₂ NSs work collaboratively to result in the boosted light-induced H₂ evolution. Results will be of immediate benefit in the rational design and preparation of vdWHs for applications in catalysis/(opto)electronics. |
Keywords: | 2D/2D van der Waals heterostructures; atomic-level S active sites; photocatalytic hydrogen evolution; rhenium disulfide |
Rights: | © 2021 Wiley-VCH GmbH |
DOI: | 10.1002/smll.202100296 |
Grant ID: | http://purl.org/au-research/grants/arc/FL170100154 http://purl.org/au-research/grants/arc/DE200100629 |
Published version: | http://dx.doi.org/10.1002/smll.202100296 |
Appears in Collections: | Aurora harvest 8 Chemical Engineering publications |
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