Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/66430
Citations | ||
Scopus | Web of Science® | Altmetric |
---|---|---|
?
|
?
|
Type: | Journal article |
Title: | Self-assembled metallo-macrocycle based coordination polymers with unsymmetrical amide ligands |
Author: | Abdul-Kadir, M. Hanton, L.R. Sumby, C.J. |
Citation: | Dalton Transactions: an international journal of inorganic chemistry, 2011; 40(45):12374-12380 |
Publisher: | Royal Society of Chemistry |
Issue Date: | 2011 |
ISSN: | 1477-9226 1477-9234 |
Abstract: | A series of metallo-macrocyclic based coordination polymers has been prepared from flexible amide ligands N-6-[(3-pyridylmethylamino)carbonyl]-pyridine-2-carboxylic acid (L1-CH(3)) and N-6-[(4-pyridylmethylamino)carbonyl]-pyridine-2-carboxylic acid (L2-CH(3)). In all but one case, self-assembled dinuclear metallo-macrocyclic units form the basis of the polymeric structures, whereby discrete metal centres, and dinuclear or trinuclear clusters, are linked by the self-assembled macrocycles to give 1D and 2D coordination polymers. In one instance, a 1D coordination polymer is formed in a reaction carried out under ambient conditions; when the same reaction is conducted under solvothermal conditions a 2D structure is formed. In all but two of these structures, the polymeric chains and nets are close-packed within the crystals. In the case of a 6,3-connected 2D coordination polymer {[Cd(3)(L2-CH(3))(3)(NO(3))(L2)(CH(3)OH)](NO(3))(2)·12½H(2)O}(n) (9), small oval channels percolate down the a-axis of the unit cell. |
DOI: | 10.1039/c1dt10853k |
Grant ID: | http://purl.org/au-research/grants/arc/FT0991910 |
Published version: | http://dx.doi.org/10.1039/c1dt10853k |
Appears in Collections: | Aurora harvest 5 Environment Institute publications IPAS publications |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.