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http://hdl.handle.net/2445/108108| Title: | Preparation and Double Michael Addition Reactions of a Synthetic Equivalent of Nazarov Reagent |
| Author: | Amat Tusón, Mercedes Arioli, Federica Pérez Bosch, Maria Molins i Grau, Elies Bosch Cartes, Joan |
| Keywords: | Indicadors (Química) Proves i reactius químics Lactames Indicators and test-papers Chemical tests and reagents Lactams |
| Issue Date: | 25-Apr-2013 |
| Publisher: | American Chemical Society |
| Abstract: | A synthetic equivalent of the Nazarov reagent, the silyl derivative 2, able to undergo base-catalyzed double Michael addition reactions with a,b-unsaturated carbonyl compounds, has been developed. The new reagent satisfactorily reacts with unsaturated indolo[2,3-a]quinolizidine lactams to give pentacyclic yohimbinone-type derivatives. |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1021/ol400934c |
| It is part of: | Organic Letters, 2013, vol. 15, num. 10, p. 2470-2473 |
| URI: | http://hdl.handle.net/2445/108108 |
| Related resource: | https://doi.org/10.1021/ol400934c |
| ISSN: | 1523-7060 |
| Appears in Collections: | Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica) Articles publicats en revistes (Nutrició, Ciències de l'Alimentació i Gastronomia) |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 624064.pdf | 232.51 kB | Adobe PDF | View/Open |
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