Skip to main content
Log in

Evolved gas analysis (EGA) of brick clays

  • Published:
Journal of thermal analysis Aims and scope Submit manuscript

Abstract

Using a system based on non-dispersive infrared (NDIR) detectors, evolved gas analysis (EGA) was able to identify and quantify the principal volatiles produced by heating powdered samples of UK brick clays. From these results, atmospheric emissions likely to result from brick production can be predicted. In addition, EGA results for extruded brick clay test pieces are significantly different from those of powdered samples. Within an extruded brick clay body, evolved gases are contained within a pore system and evolved gas-solid phase reactions also occur. This EGA study provides further evidence on the nature of firing reactions within brick clay bodies. The qualitative and quantitative influence of heating rate — a key process condition in brick manufacture — on gas release is also outlined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R. Sladek, Ceramic Forum Int., 62 (1985) 404.

    Google Scholar 

  2. J. Mullens, J. Yperman, R. Carleer, D. Franco and L. C. Van Poucke, Appl. Clay Sci., 8 (1993) 91.

    Article  Google Scholar 

  3. D. J. Morgan, J. Thermal Anal., 12 (1977) 245.

    Article  Google Scholar 

  4. A. E. Milodowski and D. J. Morgan, Nature 286 (1980) 248.

    Article  Google Scholar 

  5. E. M. Barrall and L. B. Rogers, J. Inorg. Nucl. Chem., 28 (1966) 41.

    Article  Google Scholar 

  6. D. Dollimore, Differential Thermal Analysis, Vol. 1: Fundamental Aspects. Chapter 13. Oxysalts. Pp 396–426 in: R. C. Mackenzie (Ed.). Academic Press, London and New York 1970.

    Google Scholar 

  7. J. Chiu and C. S. McLaren, Thermochim. Acta, 101 (1986) 231.

    Article  Google Scholar 

  8. Anon. Time-temperature-transformation diagrams for brick, tile and pipe clays: their determination and use. Future Practice Report 35, Energy Efficiency Enquiries Bureau, Harwell, Oxfordshire 0X11 0RA, UK. 1993, 53 pp.

  9. J. M. Ridgeway, Common Clay and Shale. Mineral Resources Consultative Committee: Mineral Dossier 22. HMSO, London 1982, pp. 164.

    Google Scholar 

  10. J. E. Prentice, Trans. Instn. Min. Metall. (Sect. B: Appl. Earth Sci.), 97 (1988) B9–14.

    Google Scholar 

  11. A. C. Dunham, Proc. Yorks. Geol. Soc., 49 (1992) 95.

    Google Scholar 

  12. R. M. S. Perrin, The Clay Mineralogy of British Sediments. Mineralogical Society (Clay Minerals Group), London (1971).

    Google Scholar 

  13. J. C. Schouten, G. Hakvoort, P. J. M. Valkenburg and C. M. Van Den Bleek, Thermochim. Acta, 114 (1987) 171.

    Article  Google Scholar 

  14. L. Heller-Kallai, I. Miloslawski and Z. Aizenshtat Clay Miner., 22 (1987) 339.

    Google Scholar 

  15. R. C. Mackenzie, L. Heller-Kallai and E. E. Lachowski, Appl. Clay Sci., 6 (1991) 69.

    Article  Google Scholar 

  16. R. W. Taylor, A. K. Burnham, R. G. Mallon and C. J. Morris, Fuel, 61 (1982) 781.

    Article  Google Scholar 

  17. J. A. Bain and D. E. Highley, Proc. Int. Clay Conf. Oxford 1978, Elsevier, Amsterdam 1979, pp. 437–446.

    Google Scholar 

  18. P. S. Nicholson and W. A. Ross, J. Am. Ceram. Soc., 53 (1970) 154.

    Google Scholar 

  19. C. Beardmore and R. W. Ford, Br. Ceram. Trans. J., 85 (1986) 137.

    Google Scholar 

  20. D. Hauck and E. Hilker, Ziegelindustrie Int., 7–8/86 (1986) 376.

    Google Scholar 

  21. J. P. Storer-Folt, D. J. Cooper and E. Boeck, Ceramic Bull., 71 (1992) 636.

    Google Scholar 

  22. D. W. Matson, D. W. Muenow and M. O. Garcia, Contrib. Mineral. Petrol., 93 (1986) 399.

    Article  Google Scholar 

  23. F. J. Wicks and R. A. Ramik, in: Thermal Analysis in Clay Science (J. W. Stucki and D. L. Bish, Eds). The Clay Minerals Society, Boulder, Colorado 1990, pp. 160–189.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Dedicated to Dr. Robert Mackenzie on the occasion of his 75th birthday

Rights and permissions

Reprints and permissions

About this article

Cite this article

Parsons, A.J., Inglethorpe, S.D.J., Morgan, D.J. et al. Evolved gas analysis (EGA) of brick clays. Journal of Thermal Analysis 48, 49–62 (1997). https://doi.org/10.1007/BF01978965

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01978965

Keywords

Navigation