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Isotopic estimation of the anthropogenic effect on the quality of groundwater in the Skhira agricultural region -Sfax (Tunisia)

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Abstract

The Skhira region is an agricultural area with interesting groundwater reserves. This water is also used for domestic and industrial purposes which contribute to its contamination. The present paper evaluates the hydrogeochemical characteristics of groundwater of the Skhira zone to investigate the impact of anthropogenic and natural sources of contamination and their suitability for drinking and for crop irrigation. Groundwater samples were collected from 30 wells distributed in the agricultural areas of the Skhira region in the dry season (August 2017). In the laboratory, the cation, anion, heavy metal, and the bacteriological analyses were performed and results were compared with the WHO standard for drinkability to determine whether the water in this system is within the acceptable limit for human consumption and irrigation by using some calculated indexes. Moreover, a multi-isotopic approach was employed to identify the main sources of pollution affecting the groundwater resources of the area. Chlorinated and sulfated calcium facies (Cl-SO4-Ca) were found for the majority of samples except some wells that showed a sodium chloride facies (Na-Cl). The high electrical conductivity pleading for a high salinity level is related to Na-Cl dissolution or to a cation exchange process. The source of nitrate is attributed to soil-N, fertilizer overuse in agriculture and manure. In fact, most samples showed to be affected by some organic source related with fecal pollution, confirmed by bacteriological and boron isotope analyses. However, due to the location of some sampling points close to the seawater, boron from seawater or marine aerosol cannot be discarded. Also, dissolved sulfate analyses, the Cl− versus SO42−, and Cl− versus Na+ showed a natural geogenic origin in the majority of samples. Overall, water quality was proved unsuitable for drinking in most sampling stations and for irrigation in some of them. The high concentrations of trace elements in these drinking waters have serious effects on the health of consumers. Therefore, it is advisable to study the trace element concentrations in this water and their relationship with health risk assessment.

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References

  • Added A, Hamza MH (1999) Evaluation of the vulnerability to pollution in Metline aquifer. (North-East of Tunisia). http://gis.esri.com/library/userconf/proc99/proceed/ -papers/pap 845_845

  • Aravena R, Robertson WD (1998) Use of multiple isotope tracers to evaluate denitrification in ground water: study of nitrate from a large-flux septic system plume. Ground Water 36:975–982

    Article  Google Scholar 

  • Ayadi R, Trabelsi R, Zouari K, Saibi H, Itoi R, Khanfir H (2017) Hydrogeological and hydrochemical investigation of groundwater using environmental isotopes (18O, 2H, 3H, 14C) and chemical tracers: a case study of the intermediate aquifer, Sfax, southeastern Tunisia. Hydrogeol J 26:983–1007

    Article  Google Scholar 

  • Babiker IS, Mohamed MAA, Hiyama T, Kato K (2005) A GIS-based DRASTIC model for assessing aquifer vulnerability in Kakamigahara Heights. Gifu Prefecture. Central Japan. Sci Total Environ 345:127–140

    Article  Google Scholar 

  • Barbieri M (2019) Isotopes in hydrology and hydrogeology. Water (Switzerland) 11(2):291. https://doi.org/10.3390/w11020291

    Article  Google Scholar 

  • Ben Akacha M (2001) Geological study of the Agareb-Sfax region: geomorphological, neotectonic and paleogeographic evolution. DEA Faculty of Sciences of Sfax Tunisia 94

  • Blavoux B, Letolle R (1995) Contribution of isotopic techniques to the knowledge of groundwater. Géochronique 54:12–15

    Google Scholar 

  • Böttcher J, Strebel OL, Voerkelus S, Schmidt HL (1990) Using isotope fractionation of nitratenitrogen and nitrate-oxygen for evaluation of microbial denitrification in sandy aquifer. J Hydrodyn 144:413–424

    Article  Google Scholar 

  • Bouchaou L, Michelot JL, Vengosh A, Hsissou Y, Qurtobi M, Gaye CB, Bullen TD, Zuppi GM (2008) Application of multiple isotopic and geochemical tracers for investigation of recharge, salinization, and residence time of water in the Souss–Massa aquifer. Southwest of Morocco. J Hydrol 352:267–287

    Article  Google Scholar 

  • Burollet P.F (1956) Contribution to the stratigraphic study of central Tunisia 8

  • Carrey R, Otero N, Soler A, Gómez-Alday JJ, Ayora C (2013) The role of lower cretaceous sediments in groundwater nitrate attenuation in central Spain: column experiments. Appl Geochem 32:142–152

    Article  Google Scholar 

  • Clark ID, Fritz P (1997) Environmental isotopes in hydrogeology. Lewis Publishers, New York

    Google Scholar 

  • Craig H (1961) Isotopic variations in meteoric waters. Science 133:1702–1703

    Article  Google Scholar 

  • DGRE. Directorate General of Water Resources (2003) Groundwater quality monitoring network. Ministry of Agriculture and Water Resources

  • Dogramaci SS, Herczeg AL, Schiff SL, Bone Y (2001) Controls on ∂34S and ∂18O of dissolved SO4 in aquifers of the Murray Basin. Australia and their use as indicators of flow processes. Appl Geochem 16:475–488

    Article  Google Scholar 

  • Dotsika E, Poutoukis D, Michelot JL, Kloppmann W (2006) Stable isotope and chloride, boron study for tracing sources of boron contamination in groundwater: boron contents in fresh and thermal water indifferent areas of Greece. Water Air Soil Pollut 174:19–32

    Article  Google Scholar 

  • Gourcy L, Petelet G (2011) Use of isotopic tools for the delineation of feeding areas of catchments intended for the supply of drinking water. Report BRGM / RP-59729-EN. 62

  • Guergazi S, Achour S (2005) Physico-chemical characteristics of the drinking water of the city of biskra, practice of chlorination .mlarhyss journal. ISSN 1112_3680

  • Hao X, Change C (2002) Does long-term heavy cattle manure application increase salinity of a clay loam soil in semi-arid southern Alberta? Agric Ecosyst Environ 1934:1–16

    Google Scholar 

  • Hem J.D. (1985) Study and interpretation of the chemical characteristics of natural water. US 434 Geological Survey Water-Supply Paper 2254, Washington, DC, USA. 264

  • Hern J, Feltz HR (1998) Effects of irrigation on the environment of selected areas of the western United States and implications to world population growth and food production. Environ Manag J52:353–360

    Google Scholar 

  • Karray I (2000) Study of the environmental vulnerability of the Skhira water table. CRDA. Regional Commissariat for Agricultural Development of Sfax. 2017. Internal report

  • Kendall C, Elliot EM, Wankel SD (2007) Tracing anthropogenic inputs of nitrogen to ecosystems. In: Michener RH, Lajtha K (eds) Stable isotopes in Ecology and Environmental Science, second edn. (Chapter 12). Blackwell, Oxford, pp 375–449

    Chapter  Google Scholar 

  • Mariotti A, Landreau A, Simon B (1988) 15N isotope biogeochemistry and natural denitrification process in groundwater: application to the chalk aquifer of northern France. Geochim Cosmochim Acta 52:1869–1878

    Article  Google Scholar 

  • Mastromatteo E, Sullivan F (1994) Summary: international symposiumon the health effects of boron and its compounds. Environ Health Perspect 102(Suppl 7):139–141

    Article  Google Scholar 

  • McIlvin MR, Altabet MA (2005) Chemical conversion of nitrate and nitrite to nitrous oxide for nitrogen and oxygen isotopic analysis in freshwater and seawater. Anal Chem 77(17):5589–5595

  • Mengis M, Schiff SL, Harris M, English MC, Aravena R, Elgood RJ, Maclean A (1999) Multiple geochemical and isotopic approaches for assessing ground water NO3- elimination in a riparian zone. Ground Water 37:448–457

    Article  Google Scholar 

  • Nigro A, Sappa G, Barbieri M (2017) Application of boron and tritiumisotopes for tracing landfill contamination in groundwater. J Geochem Explor 172:101–108

    Article  Google Scholar 

  • Paliwal K.V (1972) Irrigation with saline water. Monogram no . 2 (New series) . New Delhi. IARI.198

  • Pauwels H, Foucher J.C, Kloppmann W (2000) Denitrification and mixing in a schist aquifer: influence on water chemistry and isotopes. Chem Geol 168. 307–324

  • Pierre C, Taberner C, Urquiola MM, Pueyo JJ (1994) Sulphur and oxugen isotope composition of sulphates in hypersaline environments, as markers of redox depositional versus diagenetic changes. Mineral Mag 58(A):724–725

    Article  Google Scholar 

  • Pittalis D, Carrey R, Da Pelo S, Carletti R, Biddau R, Cidu R, Celico F, Soler A, Ghiglieri G (2018) Hydrogeologial and multi-isotopic approach to define nitrate pollution and denitrification processes in a coastal aquifer (Sardinia, Italy). Hydrogeol J 26:2021–2040

    Article  Google Scholar 

  • Ragunath HM (1987) Groundwater. Wiley Eastern Ltd, New Delhi, p 563

    Google Scholar 

  • Rajmohan N, Elango L (2004) Identification and evolution of hydro-geochemical processes in the groundwater environment in an area of the Palar and Cheyyar River Basin, Southern India. Environ Geol 46:47–61

    Google Scholar 

  • Re SE (2017) Tackling the salinity–pollution nexus in coastal aquifers from arid regions using nitrate and boron isotopes. EnvironSci Pollut Res 24:13247–13261. https://doi.org/10.1007/s11356-017-8384-z

    Article  Google Scholar 

  • Regional Commissariat for Agricultural Development of Sfax CRDA (2011) Internal report

  • Regional Commissariat for Agricultural Development of Sfax CRDA (2018) Internal report

  • Richards L. A (1954) Diagnosis and improvement of saline alkali soils. US Department of Agriculture. Hand Book

  • Ricolfi L, Barbieri M, Muteto PV, Nigro A, Sappa G, Vitale S (2020) Potential toxic elements in groundwater and their health risk assessment in drinking water of Limpopo National Park, Gaza Province, Southern Mozambique. Environ Geochem Health. https://doi.org/10.1007/s10653-019-00507-z

  • Saeedi M, Sharifi OA, Meraji H (2010) Development of groundwater quality index. Environ Monit Assess 163:327–335

    Article  Google Scholar 

  • Sghari A, Chandoul S, Mansour R (2009) Inappropriate development options in arid environments: consequences and alternatives, the case of Skhira and the region (Gulf of Gabes, Tunisia); Drought vol.20. n° 2. April May June 2009. 190_8

  • SMEWW (1998) . Standard Methods for the Examination of Water and Wastewater. American Public Health Association/American Water Works Association/ Water Environment Federation. 21st edition. Washington, DC, USA

  • Stumm W, Morgan JJ (1981) Aquatic chemistry, 2nd edn. Wiley, New York

    Google Scholar 

  • Takrouni M, Michelot JL, Maliki A, Zouari K (2003) Relationship between deep aquifer, superficial aquifers and marine intrusion in the Sfax basin (Tunisia). Hydrol Mediterr Semi arid Reg 278:1–7

    Google Scholar 

  • Todd K (1980) Groundwater hydrology, J. Wiley & Sons. 2nd Edition. New York. USA

  • Trabelsi R, Abid K, Zouari K, Yahyaoui H (2012) Groundwater salinization processes in shallow coastal aquifer of Djeffara plain of Medenine, Southeastern Tunisia. Environ Earth Sci 66(2):641–653

    Article  Google Scholar 

  • US EPA (1985) United States Environmental Protection Agency. DRASTIC: a standard system for evaluating groundwater potential using hydrogeological settings. WA/EPA Series, n° 163. Ada. Oklahoma

  • Vengosh A, Kloppmann W, Marei A, Livshitz Y, Gutierrez A, Banna M, Guerrot C, Pankratov I, Raanan H (2005) Sources of salinity and boron in the Gaza strip: natural contaminant flow in the southern Mediterranean coastal aquifer. Water Resour Res 41:W01013. https://doi.org/10.1029/2004WR003344

    Article  Google Scholar 

  • Vitòria L, Otero N, Soler A, Canals A (2004) Fertilizer characterization: isotopic data (N, S, O, C, and Sr). Environ Sci Technol 38:3254–3262

    Article  Google Scholar 

  • Vitòria L, Soler A, Canals A, Otero N (2008) Environmental isotopes (N, S, C, O, D) to determine natural attenuation processes in nitrate contaminated waters: example of Osona (NE Spain). Appl Geochem 23:3597–3611

  • Wassenaar LI (1995) Evaluation of the origin and fate of nitrate in the abbotsford aquifer using the isotopes of 15N and 18O in NO3−. Appl Geochem 10:391–405

    Article  Google Scholar 

  • WHO. World Health Organization (2011) WHO guidelines for drinking water quality

  • Widory D, Kloppmann W, Chery L, Bonnin J, Rochdi H (2004) Nitrates in groundwater: anisotopic multi-tracer approach. J Contam Hydrol 72:165–188

    Article  Google Scholar 

  • Wilcox L.V (1955) Classification and use of irrigation water. US .Department of Agri. Circ. 696. Washington. DC

  • Yangui H, Zouari K, Trabelsi R, Rozanski K (2010) Recharge mode and mineralization of groundwater in a semi-arid region: Sidi Bouzid plain (central Tunisia). Environ Earth Sci J 63:969–979

    Article  Google Scholar 

  • Zairi M, Karray I, Ben Dhia H (2005) Participatory evaluation of the impact of water and soil conservation works (CES) in the region of Sidi M'hadheb (South-East Tunisia); Drought vol.16, n ° 1. January 2005:1–8

    Google Scholar 

  • Zébidi H (1989) Hydrologie de la nappe profonde de Sfax. Rapport. La Direction Générale de Ressource en Eaux, Tunis, 27

  • Zouari K, Aranyossy JF, Mamou A, Fontes, JCH (1985) Etude isotopique et géochimique des mouvements et de l’évolution des solutions de la zone H. El Mejri et al. / Quaternary International 338 (2014) 88e98 97 aérée des sols sous climat semi-aride (Sud tunisien). In: Stable and Radioactive Isotopes in the Study of the Unsaturated Soil Zone, pp. 121e144. IAEATECDOC-357, Vienna

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Funding

This study was financially supported by the Laboratory of Eremology and Combating Desertification, Institute of Arid Regions Medenine, Tunisia and by the group of Applied Mineralogy and Environment-SGR Applied Mineralogy and Fluid Geochemistry-Department of Mineralogy, Petrology and Applied Geology, Faculty of Earth Sciences- Barcelona University.

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Authors and Affiliations

  1. Institute of Arid Regions (IRA), Laboratory of Eremology and Combating Desertification, Road of Djorf Km 22.5, Medenine, Tunisia

    Yousra Souidi, Hanen Jarray, Mohamed Loumerem & Mohamed Moussa

  2. Faculty of Sciences of Sfax, department of geology, University of Sfax, Road of Soukra km 4, 3000, Sfax, Tunisia

    Yousra Souidi & Hafedh Rigane

  3. Faculty of Earth Sciences-Department of Mineralogy Petrology and Applied Geology, University of Barcelona, Street of Martí and Franquès s/n, 08028, Barcelona, Spain

    Raul Carrey, Manuela Barbieri & Albert Soler Gil

  4. Regional Commissariat for Agricultural Development Sfax- Water resource department, Street Commandant Béjaouï, 3018, Sfax, Tunisia

    Olfa Larayedh

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  1. Yousra Souidi
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Correspondence to Hafedh Rigane.

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Souidi, Y., Jarray, H., Rigane, H. et al. Isotopic estimation of the anthropogenic effect on the quality of groundwater in the Skhira agricultural region -Sfax (Tunisia). Arab J Geosci 13, 470 (2020). https://doi.org/10.1007/s12517-020-05527-z

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