Abstract
In this case study, silica concentration, oxygen and strontium isotopes of water samples were used to study surface water–groundwater interaction at the Xin’an karst water system. The silica concentration in rain water is commonly less than 1 mg/l. In the areas around the south tributary of the Zhuozhang River, silica concentrations in the groundwater in Quaternary aquifers range between 4.04 and 7.66 mg/l while that of the surface water varies from 1.49 to 6.9 mg/l. Silica concentrations of most surface water samples increase with TDS, indicating the effect of groundwater recharge on river water chemistry. On the contour map of silica concentration of groundwater in Quaternary aquifers, samples located close to surface water often have lower silica concentrations as a result of surface water recharge. Both overland flow and surface water have impact on karst water according to our hydrogeochemical study of stable oxygen isotope, Sr isotope and strontium contents. Calculation results of three end member mixing model show that the contribution of karst water, surface water and overland flow water is 45, 28 and 27%, respectively.
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References
Abu-Jaber N (2001) Geochemical evolution and recharge of the shallow aquifers at Tulul al Ashaqif, NE Jordan. Env Geol 41:372–383
Asano Y, Ohte N, Uchida T (2004) Sources of weathering-derived solutes in two granitic catchments with contrasting forest growth. Hydrol Proc 18:651–666
Banner JL, Musgrove M, Capo RC (1994) Tracing ground-water evolution in a limestone aquifer using Sr isotopes: effects of multiple sources of dissolved ions and mineral-solution reactions. Geology 22:687–690
Blum JD, Erel Y, Brown K (1994) 87Sr/86Sr ratios of Sierra Nevada stream waters: implications for relative mineral weathering rates. Geochim Cosmochim Acta 57:5019–5025
Böhlke JK, Horan M (2000) Strontium isotope geochemistry of groundwaters and streams affected by agriculture, Locust Grove, MD. Appl Geochem 15:599–609
Bullen TD, Krabbenhoft DP, Kendall C (1996) Kinetic and mineralogic controls on the evolution of groundwater chemistry and 87Sr/86Sr in a sandy silicate aquifer, northern Wisconsin, USA. Geochim Cosmochim Acta 60:1807–1821
Chaudhuri S (1978) Strontium isotopic composition of several oilfield brines in sedimentary basins. Geochim Cosmochim Acta 42:329–331
Clark ID, Fritz P (1997) Environmental isotopes in hydrogeology. Lewis, New York
Dobrzyński D (2005) Silica origin and solubility in groundwater from the weathered zone of sedimentary rocks of the Intra-Sudetic Basin, SW Poland. Acta Geologica Polonica 55:445–462
Epstein S, Mayeda TK (1953) Variations of the 18O content of waters from natural sources. Geochim Cosmochim Acta 4:213–224
Faure G (1986) Principles of isotope geology. John Wiley & Sons, New York
Freeze RA, Cherry JA (1979) Groundwater. Prentice-Hall, Inc, Englewood Cliffs, New Jersey
Goldstein SJ, Jacobsen SB (1987) The Nd and Sr isotopic systematics of river water dissolved material: Implications for the sources of Nd and Sr in seawater. Chem Geol (Isotope Geoscience Section) 66:245–272
Heidel C, Tichomirowa M, Matschullat J (2007) Lead and strontium isotopes as indicators for mixing processes of waters in the former mine ‘Himmelfahrt Fundgrube’, Freiberg (Germany). Isot Environ Health Stud 43:339–354
Hinton MJ, Shiff SL, English MC (1994) Examining the contribution of glacial till water to storm runoff using two- and three-component hydrograph separation. Water Res R 30:983–993
Horst A, Mahlknecht J, Merkel BJ (2007) Estimating groundwater mixing and origin in an overexploited aquifer in Guanajuato, Mexico, using stable isotopes (strontium-87, carbon-13, deuterium and oxygen-18). Isot Environ Health Stud 43:323–338
Johnson TM, DePaolo DJ (1997) Rapid exchange effects on isotope ratios in groundwater systems, 1. Development of a transport-diffusion-exchange model. Water Res R 33(1):187–195
Katz BG, Bullen TD (1996) The combined use of 87Sr/86Sr and carbon and water isotopes to study the hydrochemical interaction between groundwater and lakewater in mantled karst. Geochim Cosmochim Acta 60:5075–5087
Leung CM, Jiao JJ (2006) Use of strontium isotopes to identify buried water main leakage into groundwater in a highly urbanized coastal area. Environ Sci Technol 40:6575–6579
Marchand G (2001) Groundwater–surface water interaction and nitrate origin in municipal water supply aquifers, San José, Costa Rica. MSc thesis, University of Calgary, Canada
Mazor E (1997) Chemical and isotopic groundwater hydrology: the applied approach, 2nd edn. Marcel Dekker, Inc, New York
McNutt RH, Frape SK, Fritz P, Jones MG, MacDonald IM (1990) The 87Sr/86Sr value of Canadian Shield brines and fracture minerals with applications to groundwater mixing, fracture history, and geochronology. Geochim Cosmochim Acta 54:205–215
Négrel P, Lachassagne P (2000) Geochemistry of the Maroni River (French Guiana) during the low water stage: implications for water–rock interaction and groundwater characteristics. J Hydrol 237:212–233
Négrel P, Petelet-Giraud E, Barbier J, Gautier E (2003) Surface water–groundwater interactions in an alluvial plain: Chemical and isotopic systematics. J Hydrol 277:248–267
Ojiambo SB, Lyons WB, Welch KA, Poreda RJ, Johannesson KH (2003) Strontium isotopes and rare earth elements as tracers of groundwater–lake water interactions, Lake Naivasha, Kenya. Appl Geochem 18:1789–1805
Parkurst DL, Appelo CAJ (1999) User’s guide to PHREEQC (Version 2)—a computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations. US Geological Survey Water-Resources Investigations Report (a report)
Shand P, Love AJ, Darbyshire DPF, Edmunds WM (2007) Sr isotopes in natural waters: applications to source characterisation and water–rock interaction in contrasting landscapes. In: Bullen TD, Wang Y (eds) Water–rock interaction. Taylor and Francis, London, pp 27–35
Stueber AM, Pushkar P, Hetherington EA (1987) A strontium isotopic study of formation waters from the Illinois basin, USA. Appl Geochem 2:477–494
Turekian KK, Kulp JL (1956) The geochemistry of strontium. Geochim Cosmochim Acta 10:245–296
Uliana MM, Banner JL, Sharp JM Jr (2007) Regional groundwater flow paths in Trans-Pecos, Texas inferred from oxygen, hydrogen, and strontium isotopes. J Hydrol 334:334–346
Wang Y, Ma T, Luo Z (2001) Geostatistical and geochemical analysis of surface water leakage into groundwater on a regional scale: a case study at the Liulin karst water system, northwestern China. J Hydrol 246:223–234
Wang Y, Guo Q, Su C, Ma T (2006) Strontium isotope characterization and major ion geochemistry of karst water flow, Shentou, northern China. J Hydrol 328:592–603
Wels C, Cornett RJ, Lazerte BD (1991) Hydrograph separation: a comparison of geochemical and isotopic tracers. J Hydrol 122:253–274
Wu P (2006) Hydrogeochemistry of surface water and groundwater interaction in Xin’an spring system. PhD thesis, China University of Geosciences (in Chinese with English abstract)
Acknowledgments
The research work was financially supported by National Natural Science Foundation of China (No. 40830748), Ministry of Science and Technology of China (No. 2008KR0426) and Ministry of Education of China (111 project).
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Gao, X., Wang, Y., Wu, P. et al. Trace elements and environmental isotopes as tracers of surface water–groundwater interaction: a case study at Xin’an karst water system, Shanxi Province, Northern China. Environ Earth Sci 59, 1223–1234 (2010). https://doi.org/10.1007/s12665-009-0111-8
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DOI: https://doi.org/10.1007/s12665-009-0111-8