LetterThe calcite (10l̄4) cleavage surface in water: Early results of a crystal truncation rod study
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Cited by (39)
X-ray scattering of calcite thin films deposited by atomic layer deposition: Studies in air and in calcite saturated water solution
2014, Thin Solid FilmsCitation Excerpt :Consequently, carbonates have been the focus of a great deal of research. Approaches including, but not limited to, phase transition studies [13,14], vibrational spectroscopy [15–17], X-ray reflectivity [18–25], atomic force microscopy [26–29] and theoretical modeling [30–38] have been implemented to resolve the fundamental physical and chemical properties of carbonates. Many of the processes in which carbonates are important occur on the micro-scale at and along fluid interfaces and grain boundaries.
Calcite (104)-water interface structure, revisited
2012, Geochimica et Cosmochimica ActaCitation Excerpt :Computational studies predict that this should cause substantial lattice displacements near the surface (Wright et al., 2001). Numerous experimental (Chiarello and Sturchio, 1995; Fenter et al., 2000; Geissbuhler et al., 2004; Magdans et al., 2006; Heberling et al., 2011) and computational studies (Wright et al., 2001; Cygan et al., 2002; Kerisit et al., 2003; Kerisit and Parker, 2004; Rahaman et al., 2008; Lardge et al., 2009; Cooke et al., 2010; Gale et al., 2011) have confirmed that specific adsorption of water compensates the under-coordinated surface Ca ions. This surface complexation of water to under-coordinated metal ions is common to many mineral–water interfacial systems (Fenter and Sturchio, 2004).
Mineral-water interfacial structures revealed by synchrotron X-ray scattering
2004, Progress in Surface ScienceCitation Excerpt :A significant advantage of these sample geometries is that they allow measurement under equilibrium, or near-equilibrium, conditions. Under these circumstances, damage that is imparted to the crystal surface by the X-ray beam (e.g., roughening) can heal and return to the equilibrium state [220]. In some cases, care must be taken with the thin-film cell to ensure that the environment above the plastic window is controlled to present modifications to the solution chemistry by reactions with atmospheric gases (e.g., CO2) that diffuse through the plastic window.
Understanding crystal growth in vacuum and beyond
2002, Surface ScienceMn and Zn incorporation into calcite as a function of chloride aqueous concentration
2000, Geochimica et Cosmochimica ActaAtomic-scale structure of the orthoclase (001)-water interface measured with high-resolution X-ray reflectivity
2000, Geochimica et Cosmochimica Acta