Hostname: page-component-8448b6f56d-c47g7 Total loading time: 0 Render date: 2024-04-23T11:51:50.949Z Has data issue: false hasContentIssue false
  • English
  • Français

Role of Iron Oxides in the Phosphate Adsorption Properties of Kaolinites From the Ivory Coast

Published online by Cambridge University Press:  01 January 2024

J. Sei ,
J. C. Jumas ,
J. Olivier-Fourcade ,
H. Quiquampoix  and
S. Staunton
J. Sei*
Affiliation:
LPMC Université Montpellier II, place E. Bataillon, C.C. 03, 34095 Montpellier Cedex 5, France Unité de Science du Sol, INRA, place P. Viala, 34060 Montpellier Cedex 1, France
J. C. Jumas*
Affiliation:
LPMC Université Montpellier II, place E. Bataillon, C.C. 03, 34095 Montpellier Cedex 5, France
J. Olivier-Fourcade*
Affiliation:
LPMC Université Montpellier II, place E. Bataillon, C.C. 03, 34095 Montpellier Cedex 5, France
H. Quiquampoix
Affiliation:
Unité de Science du Sol, INRA, place P. Viala, 34060 Montpellier Cedex 1, France
S. Staunton*
Affiliation:
Unité de Science du Sol, INRA, place P. Viala, 34060 Montpellier Cedex 1, France
*
†Present address: Laboratoire de Chimie Minérale, Université de Cocody, 22 BP 582, Abidjan 22, Ivoire Coast
‡Present address: LAMMI (UMR 5072), Université Montpellier II, Place E. Bataillon, C.C. 15, 34095 Montpellier Cedex 5, France
‡Present address: LAMMI (UMR 5072), Université Montpellier II, Place E. Bataillon, C.C. 15, 34095 Montpellier Cedex 5, France
*E-mail address of corresponding author: staunton@ensam.inra.fr
Get access Rights & Permissions [Opens in a new window]

Abstract

The phosphate adsorption properties of three clay samples, with kaolinite as the dominant mineral, from different deposits in the Ivory Coast have been investigated. The clays contain varying amounts of crystalline Fe oxides and kaolinite with structural Fe. All measurements were made in dilute suspension under controlled conditions of temperature, pH, ionic strength and saturating cation. Data have been fitted to Langmuir adsorption isotherms. Both P adsorption and surface area measurements have been made on samples before and after chemical removal of Fe oxides. The samples have large P adsorption capacities, which are not entirely explained by their large specific surface areas. The presence of Fe oxides makes a strong contribution to the surface area and enhances the adsorption capacities. There is little evidence that structural Fe makes a strong contribution to the enhanced P adsorption capacity.

Keywords

AdsorptionFe OxideGoethiteHematiteKaoliniteLangmuirPhosphate
Type
Research Article
Information
Clays and Clay Minerals , Volume 50 , Issue 2 , April 2002 , pp. 217 - 222
Copyright
Copyright © 2002, The Clay Minerals Society

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Barrow, N.J., (1984) Modelling the effects of pH on phosphate sorption by soils Journal of Soil Science 35 283–297 10.1111/j.1365-2389.1984.tb00283.x.10.1111/j.1365-2389.1984.tb00283.xCrossRefGoogle Scholar
Bar-Yosef, B. Kafkafi, U. Rosenberg, R. and Sposito, G., (1988) Phosphorus adsorption by kaolinite and montmorillonite: I. Effect of time, ionic strength and pH Soil Science Society of America Journal 52 1580–1585 10.2136/sssaj1988.03615995005200060011x.10.2136/sssaj1988.03615995005200060011xCrossRefGoogle Scholar
Borggaard, O.K., (1982) The influence of iron oxides on the surface area of soil Journal of Soil Science 33 443–449 10.1111/j.1365-2389.1982.tb01779.x.CrossRefGoogle Scholar
Borggaard, O.K., (1983) Effect of surface area and mineralogy of iron oxides on their surface charge and anion-adsorption properties Clays and Clay Minerals 31 230–232 10.1346/CCMN.1983.0310309.10.1346/CCMN.1983.0310309CrossRefGoogle Scholar
Borggaard, O.K., (1983) The influence of iron oxides on phosphate adsorption by soil Journal of Soil Science 34 333–341 10.1111/j.1365-2389.1983.tb01039.x.10.1111/j.1365-2389.1983.tb01039.xCrossRefGoogle Scholar
Carreira, J.A. and Lajtha, K., (1997) Factors affecting phosphate sorption along a Mediterranean, dolomitic soil and vegetation chronosequence European Journal of Soil Science 48 139–149 10.1111/j.1365-2389.1997.tb00193.x.10.1111/j.1365-2389.1997.tb00193.xCrossRefGoogle Scholar
Cabrera, F. Madrid, L. and de Arambarri, P., (1977) Adsorption of phosphate by various oxides: theoretical treatment of the adsorption envelope Journal of Soil Science 28 306–313 10.1111/j.1365-2389.1977.tb02239.x.CrossRefGoogle Scholar
Cornell, R.M. and Schwertmann, U., (1996) The Iron Oxides: Structure, Properties, Reactions, Occurrence and Uses New York VCH Weinheim 573 pp.Google Scholar
Geelhoed, J.S. Hiemstra, T. and van Riemsdijk, W.H., (1997) Phosphate and sulfate adsorption on goethite: single anion and competitive adsorption Geochimica et Cosmochimica Acta 61 2389–2396 10.1016/S0016-7037(97)00096-3.CrossRefGoogle Scholar
Goldberg, S. and Sposito, G., (1984) A chemical model of phosphate adsorption by soil: I Reference oxide minerals Soil Science Society of America Journal 48 772–778 10.2136/sssaj1984.03615995004800040015x.CrossRefGoogle Scholar
Herbillon, A.J. Mestdagh, M.M. Vielvoye, L. and Derouane, E.G., (1976) Iron in kaolinite with special reference to kaolinite from tropical soils Clay Minerals 11 201–220 10.1180/claymin.1976.011.3.03.10.1180/claymin.1976.011.3.03CrossRefGoogle Scholar
Kuo, S. and Lotse, E.G., (1972) Kinetics of phosphate adsorption by calcium carbonate and Ca-kaolinite Soil Science Society of America Proceedings 36 725–729 10.2136/sssaj1972.03615995003600050015x.CrossRefGoogle Scholar
Manning, B.A. and Goldberg, S., (1996) Modeling arsenate competitive adsorption on kaolinite, montmorillonite and illite Clays and Clay Minerals 44 609–623 10.1346/CCMN.1996.0440504.10.1346/CCMN.1996.0440504CrossRefGoogle Scholar
Mehra, O.P. and Jackson, M.L., (1960) Iron oxide removal from soils and clays by a dithionite-citrate system buffered with sodium bicarbonate Clays and Clay Minerals 7 317–327 10.1346/CCMN.1958.0070122.CrossRefGoogle Scholar
Mestdagh, M.M. Vielvoye, L. and Herbillon, A.J., (1980) Iron in kaolinite: II. The relationship between kaolinite crystallinity and iron content Clay Minerals 15 1–13 10.1180/claymin.1980.015.1.01.10.1180/claymin.1980.015.1.01CrossRefGoogle Scholar
Murphy, J. and Riley, J.P., (1962) A modified single solution method for the determination of phosphate in natural waters Analytica Chimica Acta 27 31–36 10.1016/S0003-2670(00)88444-5.10.1016/S0003-2670(00)88444-5CrossRefGoogle Scholar
Pardo, M.T. Guadalix, M.E. and Garcia-Gonzalez, M.T., (1992) Effect of pH and background electrolyte on P sorption by variable charge soils Geoderma 54 275–284 10.1016/0016-7061(92)90109-K.CrossRefGoogle Scholar
Parfitt, L.R., (1978) Anion adsorption by soils and soil materials Advanced Agronomy 30 1 50.Google Scholar
Peüa, F. and Torrent, J., (1984) Relationships between phosphate sorption and iron oxides in Alfisols from a river terrace sequence of Mediterranean Spain Geoderma 33 283–296 10.1016/0016-7061(84)90030-2.Google Scholar
Ryden, J.C. and Syers, J.K., (1975) Rationalization of ionic strength and cation effects on phosphate sorption by soils Journal of Soil Science 26 395–406 10.1111/j.1365-2389.1975.tb01963.x.10.1111/j.1365-2389.1975.tb01963.xCrossRefGoogle Scholar
Sei, J., (1998) Etude de matériaux de dimensionalité réduite: Relation structure-propriétés dans des kaolinites naturelle de Cote d’Ivoire France Univ. Montpellier.Google Scholar
Singh, B. and Gilkes, R.J., (1992) Properties of soil kaolinites from south-western Australia Journal of Soil Science 43 654 667.10.1111/j.1365-2389.1992.tb00165.xCrossRefGoogle Scholar
Torrent, J., (1997) Interactions between phosphate and iron oxide Advances in Geoecology 30 321 344.Google Scholar
Torrent, J. Barro’n, V. and Schwertmann, U., (1990) Phosphate adsorption and desorption by goethites differing in crystal morphology Soil Science Society of America Journal 54 1007–1012 10.2136/sssaj1990.03615995005400040012x.10.2136/sssaj1990.03615995005400040012xCrossRefGoogle Scholar
White, R.E., (1980) Retention and release of phosphate by soils and soil constituents Soils and Agriculture, Critical Reports on Applied Chemistry, Volume 2 Oxford, UK Blackwell Scientific Publications.Google Scholar
Yuan, G. and Lavkulich, L.M., (1994) Phosphate sorption in relation to extractable iron and aluminum in Spodosols Soil Science Society of America Journal 58 343–346 10.2136/sssaj1994.03615995005800020013x.10.2136/sssaj1994.03615995005800020013xCrossRefGoogle Scholar