{"_buckets": {"deposit": "ec6b73d1-f602-46d1-b9fd-d0a60e18fcac"}, "_deposit": {"created_by": 4, "id": "2000061", "owners": [4], "pid": {"revision_id": 0, "type": "depid", "value": "2000061"}, "status": "published"}, "_oai": {"id": "oai:hama-med.repo.nii.ac.jp:02000061", "sets": ["11"]}, "author_link": [], "control_number": "2000061", "item_3_biblio_info_5": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2022", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "5", "bibliographicPageEnd": "464", "bibliographicPageStart": "457", "bibliographicVolumeNumber": "54", "bibliographic_titles": [{"bibliographic_title": "Organic Preparations and Procedures Internationa", "bibliographic_titleLang": "en"}]}]}, "item_3_description_10": {"attribute_name": "注記", "attribute_value_mlt": [{"subitem_description": "雑誌掲載タイトル:Facile Multi-gram Preparation of trans-7,8-Dihydro-7,8-dihydroxybenzo[a]pyrene, a Precursor of Benzopyrene Diol Epoxide", "subitem_description_language": "ja", "subitem_description_type": "Other"}]}, "item_3_description_9": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Carcinogenic benzo[a]pyrene diol epoxide (BPDE) is one of the essential materials in tumor pathological research; however, it is expensive and unstable. In addition, its synthetic intermediates are metabolic intermediates of BPDE; thus, there is a need to reduce the handling of these compounds during the synthesis. Accordingly, a precursor of BPDE (i.e., trans-7,8-dihydro-7,8-dihydroxybenzo[a]pyrene) was prepared in a multi-gram scale by modified procedures. Efficient work-ups (e.g., simple extraction and precipitation) were also improved, which resulted in a crude product with high target compound content in each step of the synthesis.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_3_publisher_6": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Taylor \u0026 Francis", "subitem_publisher_language": "en"}]}, "item_3_relation_28": {"attribute_name": "出版社DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1080/00304948.2022.2081026", "subitem_relation_type_select": "DOI"}}]}, "item_3_rights_7": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "This is an Accepted Manuscript of an article published by Taylor \u0026 Francis in Organic Preparations and Procedures Internationa on 2022, available at: https://doi.org/10.1080/00304948.2022.2081026.", "subitem_rights_language": "en"}]}, "item_3_select_2": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"subitem_select_item": "Journal Article", "subitem_select_language": "en"}]}, "item_3_source_id_19": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0030-4948", "subitem_source_identifier_type": "PISSN"}]}, "item_3_source_id_20": {"attribute_name": "EISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1945-5453", "subitem_source_identifier_type": "EISSN"}]}, "item_3_source_id_23": {"attribute_name": "NII書誌ID", "attribute_value_mlt": [{"subitem_source_identifier": "AA00765353", "subitem_source_identifier_type": "NCID"}]}, "item_3_version_type_32": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Kurono, Nobuhito", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Iwashita, Yuji", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Sugimura, Haruhiko", "creatorNameLang": "en"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2023-12-21"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "OPPI-54-457.pdf", "filesize": [{"value": "304 KB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_3", "mimetype": "application/pdf", "size": 304000.0, "url": {"objectType": "fulltext", "url": "https://hama-med.repo.nii.ac.jp/record/2000061/files/OPPI-54-457.pdf"}, "version_id": "12c8a630-bc23-4697-bd2b-fa251f728d9a"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "facile preparation", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "multi-grams synthesis", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "BPDE", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "carcinogen", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "thermal instability", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Facile Preparation of Multi-grams of trans-7,8-Dihydro-7,8-dihydroxybenzo[a]pyrene, a Precursor of Benzopyrene Diol Epoxide", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Facile Preparation of Multi-grams of trans-7,8-Dihydro-7,8-dihydroxybenzo[a]pyrene, a Precursor of Benzopyrene Diol Epoxide", "subitem_title_language": "en"}]}, "item_type_id": "3", "owner": "4", "path": ["11"], "permalink_uri": "http://hdl.handle.net/10271/0002000061", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2023-12-25"}, "publish_date": "2023-12-25", "publish_status": "0", "recid": "2000061", "relation": {}, "relation_version_is_last": true, "title": ["Facile Preparation of Multi-grams of trans-7,8-Dihydro-7,8-dihydroxybenzo[a]pyrene, a Precursor of Benzopyrene Diol Epoxide"], "weko_shared_id": -1}
Facile Preparation of Multi-grams of trans-7,8-Dihydro-7,8-dihydroxybenzo[a]pyrene, a Precursor of Benzopyrene Diol Epoxide
http://hdl.handle.net/10271/0002000061
http://hdl.handle.net/10271/0002000061