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https://hdl.handle.net/10356/90202
Title: | Fusing N-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing | Authors: | Zhang, Jing Wang, Chengyuan Long, Guankui Aratani, Naoki Yamada, Hiroko Zhang, Qichun |
Keywords: | Carrier Transport Hole Mobility DRNTU::Engineering::Materials |
Issue Date: | 2016 | Source: | Zhang, J., Wang, C., Long, G., Aratani, N., Yamada, H., & Zhang, Q. (2016). Fusing N-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing. Chemical Science, 7(2), 1309-1313. doi:10.1039/C5SC03604F | Series/Report no.: | Chemical Science | Abstract: | An unexpected “kinked” N-heteroacene with a slipped two-dimensional ladder-like packing feature is produced from the conventional condensation reaction. The as-obtained compound [2,2′]bi(5,12-bis(TIPS)piperazin-3-one[2,3-b]phenazine) (2BPP) consists of two identical backbones (5,12-bis(TIPS)piperazin-3-one[2,3-b]phenazine), which are fused together through a C[double bond, length as m-dash]C double bond and two intramolecular H-bonds. A study on the charge carrier transport indicates that a 2BPP single crystal has a hole mobility up to 0.3 cm2 V−1 s−1, while theoretical calculations suggest that this compound might possess potential well-balanced ambipolar charge-transport characteristics. | URI: | https://hdl.handle.net/10356/90202 http://hdl.handle.net/10220/47187 |
ISSN: | 2041-6520 | DOI: | 10.1039/C5SC03604F | Schools: | School of Materials Science & Engineering School of Physical and Mathematical Sciences |
Rights: | © 2016 The Author(s) (published by Royal Society of Chemistry). This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
Appears in Collections: | MSE Journal Articles |
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Fusing N-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing.pdf | 640.18 kB | Adobe PDF | View/Open |
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