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Process-Dependent Photocatalytic Properties of Polymer Thin Films Containing TiO2 Nanoparticles: Dip vs Spin Self-Assembly Methods

Cited 44 time in Web of Science Cited 45 time in Scopus
Authors

Sohn, Byeong-Hyeok; Kim, Tae-Hyun; Char, Kookheon

Issue Date
2002-09-13
Publisher
American Chemical Society
Citation
Langmuir, 2002, 18, 7770-7772
Abstract
Thin films consisting of polyelectrolytes and positively charged TiO2 nanoparticles were fabricated by the dip and the spin self-assembly (SA) methods. Employing the same deposition sequence in both methods, both SA films showed a similar thickness. We observed a comparatively layered structure in the spin SA film and a fuzzy structure in the dip SA film. As the number of TiO2 nanoparticle layers was increased, the photooxidized amount of iodide and methyl orange increased in the dip SA film but not in the spin SA film due to the limited diffusion of molecules caused by its compact structure.
ISSN
0743-7463 (print)
1520-5827 (online)
Language
English
URI
https://hdl.handle.net/10371/5761
DOI
https://doi.org/10.1021/la025957p
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