Infrared spectra of cyclic-O6+ and trans-O6+ in solid neon and argon

Date

1999-05-15

Author

Zhou, Mingfei
Hacaloğlu, Jale
Andrews, Lester

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Charged transient species in the oxygen system have been trapped in solid argon and neon using electron impact, Townsend discharge, and laser-ablation methods. The previously identified O-3(-), O-4(-), and O-4(+) species are observed in these experiments. Absorptions at 1435.0 and 1429.5 cm(-1) in solid neon are characterized as cyclic-O-6(+) and trans-O-6(+), respectively, on the basis of annealing behavior, isotopic substitution, multiplet structure in mixed O-16(2) + O-18(2) experiments, and density functional calculations. Cyclic-O-6(+) is observed at 1416.1 cm(-1) in solid argon, a smaller displacement than found for cyclic-O-4(+) in solid argon. (C) 1999 American Institute of Physics. [S0021-9606(99)30518-3].

Subject Keywords

Raman, Anions, o-4+, Stabilization, Matrix-isolation, Oxygen molecules, Photo-ionization, Vibrational analysis, Ablated iron atoms, Density-functional calculations

URI

https://hdl.handle.net/11511/30450

Journal

Journal of Chemical Physics

DOI

https://doi.org/10.1063/1.478910

Collections

Graduate School of Natural and Applied Sciences, Article

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Citation Formats

M. Zhou, J. Hacaloğlu, and L. Andrews, “Infrared spectra of cyclic-O6+ and trans-O6+ in solid neon and argon,” Journal of Chemical Physics, pp. 9450–9456, 1999, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/30450.