Palladium(0) nanoparticles supported on metal organic framework as highly active and reusable nanocatalyst in dehydrogenation of dimethylamine-borane

Date

2014-04-05

Author

Gülcan, Mehmet
Zahmakıran, Mehmet
Özkar, Saim

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Palladium(0) nanoparticles supported on the external surface of Cu-3(btc)(2) framework (PdNPs@Cu-3(btc)(2)) were in-situ generated from the reduction of Pd(acac)2 precursor impregnated on the Cu-3(btc)(2) support during the dehydrogenation of dimethylamine-borane in toluene at room temperature. The characterization of PdNPs@Cu-3(btc)(2) by using advanced analytical techniques shows the formation of well-dispersed palladium(0) nanoparticles supported on Cu-3(btc)(2) surface. These new palladium(0) nanoparticles were found to be the most active and the longest-lived nanocatalyst with superior reusability performance in the dehydrogenation of dimethylamine-borane at room temperature.

Subject Keywords

Process Chemistry and Technology, General Environmental Science, Catalysis

URI

https://hdl.handle.net/11511/36945

Journal

APPLIED CATALYSIS B-ENVIRONMENTAL

DOI

https://doi.org/10.1016/j.apcatb.2013.09.007

Collections

Department of Chemistry, Article

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Citation Formats

M. Gülcan, M. Zahmakıran, and S. Özkar, “Palladium(0) nanoparticles supported on metal organic framework as highly active and reusable nanocatalyst in dehydrogenation of dimethylamine-borane,” APPLIED CATALYSIS B-ENVIRONMENTAL, pp. 394–401, 2014, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/36945.