Bromofluorocarbene addition to 6-phenylbicyclo[3.2.0]hept-6-ene: characterization and formation mechanism of the products

Download

10.3998:ark.5550190.0007.a20.pdf

Date

2006-4-5

Author

Balcı, Metin
Algı, Fatih

Metadata

Show full item record

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Item Usage Stats

94
views

64
downloads

Bromofluorocarbene addition to 6-phenylbicyclo[3.2.0]hept-6-ene provided fluoro-indanes such as 4,6-difluoro-5-phenylindane, 5,6-difluoro-4-phenylindane, 5,7-difluoro-4-phenylindane, 4-bromo-6-fluoro-5-phenylindane and 5-bromo-6-fluoro-4-phenylindane. The characterization the formation mechanism of the products are discussed.

Subject Keywords

Bromofluorocarbene, Carbene addition, Fluoro-indanes

URI

https://hdl.handle.net/11511/50918

Journal

Arkivoc

DOI

https://doi.org/10.3998/ark.5550190.0007.a20

Collections

Department of Chemistry, Article

Suggestions

OpenMETU
Core

Bromofluorocarbene addition to 6-phenylbicyclo[3.2.0]hept-6-ene: characterization and formation mechanism of the products Algi, Fatih; Balcı, Metin (2006-01-01) Bromofluorocarbene addition to 6-phenylbicyclo[3.2.0]hept-6-ene provided fluoro-indanes such as 4,6-difluoro-5-phenylindane, 5,6-difluoro-4-phenylindane, 5,7-difluoro-4-phenylindane, 4-bromo-6-fluoro-5-phenylindane and 5-bromo-6-fluoro-4-phenylindane. The characterization the formation mechanism of the products are discussed.
Manganese(III) acetate-mediated oxidative coupling of phenylhydrazines with furan and thiophene: a novel method for hetero biaryl coupling Demir, Ayhan Sıtkı; Reis, O; Emrullahoglu, M (Elsevier BV, 2002-09-30) A convenient new method for the arylation of furan and thiophene with arylhydrazine and manganese(III) acetate is described. Oxidation of arylhydrazines with Mn(III) acetate in furan or thiophene affords the corresponding 2-aryl-substituted furans and thiophenes in good yield using commercially available materials; access to 2-substituted heterobiaryls works selectively, and coupling occurs with loss of the hydrazine moiety.
Manganese(III) acetate mediated oxidative coupling of phenylhdrazines with furan and thiophene Emrullahoğlu, Mustafa; Demir, Ayhan Sıtkı; Department of Chemistry (2003) A convenient new method for the arylation of furan and thiophene with arylhydrazine and manganese(III) acetate is described. Oxidation of arylhydrazines with Mn(III) acetate in furan or thiophene affords the corresponding 2-aryl-substituted furans and thiophenes in good yield using commercially available materials; access to 2-substituted heterobiaryls works selectively, and coupling occurs with loss of the hydrazine moiety.
Heterologous expression, characterization, and optimization of production of alpha-galactosidase from aspergillus fumigatus in aspergillus sojae Gürkök, Sümeyra; Ögel, Zümrüt Begüm; Bölükbaşı, Ufuk; Department of Biotechnology (2012) α-Galactosidase is an exo-glycosidase that hydrolyses non-reducing, α-1,6-linked α-galactose units from oligosaccharides, galactomannans, and galactolipids. α-Galactosidase activity has biotechnological, industrial, and medical importance. α-Galactosidase from A. fumigatus IMI 385708, in particular, can catalyse unique hydrolysis and transgalactosylation reactions on polymeric substrates. In this study, α-galactosidase of the human pathogen A. fumigatus IMI 385708 was first produced in a GRAS organism, Aspe...
Photoinduced polymerization of thiophene using iodonium salt Yagci, Y; Yilmaz, F; Kiralp, S; Toppare, Levent Kamil (Wiley, 2005-06-16) Thiophene was polymerized by means of UVirradiation using diphenyliodonium hexafluorophosphate as a photoinitiator. An initiation mechanism involving electron transfer from photochemically generated onium radical cations to thiophene was proposed. N-Ethoxy-2-methylpyridinium hexafluorophosphate and triphenylsulfonium hexafluorophosphate were also found to be effective in facilitating the polymerization of thiophene. Polymerization is accompanied with the film formation on the surface of the reaction tube. T...

Citation Formats

M. Balcı and F. Algı, “Bromofluorocarbene addition to 6-phenylbicyclo[3.2.0]hept-6-ene: characterization and formation mechanism of the products,” Arkivoc, pp. 173–182, 2006, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/50918.