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Chiral heterobimetallic complexes of carbodiphosphoranes and phosphinidene–carbene adducts

MPS-Authors
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Alcarazo,  M.
Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Radkowski,  Karin
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Mehler,  Gerlinde
Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Goddard,  Richard
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Fürstner,  Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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c3cc40382c.txt
(Supplementary material), 210KB

Citation

Alcarazo, M., Radkowski, K., Mehler, G., Goddard, R., & Fürstner, A. (2013). Chiral heterobimetallic complexes of carbodiphosphoranes and phosphinidene–carbene adducts. Chemical Communications, 49(30), 3140-3142. doi:10.1039/c3cc40382c.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0014-A504-8
Abstract
Heterobimetallic complexes derived from carbodiphosphoranes or phosphinidene–carbene adducts are reported, in which the central atom accepts two lone-pairs from two different donor ligands and – at the same time – donates two lone-pairs to two different metal centers. Therefore these complexes are carbogenic yet captodative chiral entities.