English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

Cation-anion CH...O¯ interactions in the metal-free phenolate, tetra-n-butylammonium phenol-phenolate

MPS-Authors
/persons/resource/persons58578

Goddard,  R.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58620

Herzog,  H. M.
Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58919

Reetz,  M. T.
Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Goddard, R., Herzog, H. M., & Reetz, M. T. (2002). Cation-anion CH..O¯ interactions in the metal-free phenolate, tetra-n-butylammonium phenol-phenolate. Tetrahedron, 58(39), 7847-7850. doi:10.1016/S0040-4020(02)00900-6.


Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-9997-7
Abstract
Deprotonation of phenol by tetra-n-butylammonium hydroxide and subsequent removal of water by P2O5 results in quantitative formation of tetra-n-butylammonium phenol-phenolate. The compound crystallizes as an ion pair, with the solute phenol molecule intimately attached to the phenolate anion by an O- H...O- hydrogen bond (O...O 2.471(5) Angstrom). A short contact between one alpha-C atom of the tetra-n-butylammonium cation and the phenolate O atom indicates that the ion pair interaction is strengthened by an additional C-H...O- hydrogen- bond, despite the attached phenol. (C) 2002 Elsevier Science Ltd. All rights reserved.