Synthesis, Solid-State Structure, and Electronic Nature of a 
Phosphinine-Stabilized triangulo Palladium Cluster

Reetz, Manfred T.; Bohres, Edward; Goddard, Richard; Holthausen, Max C.; Thiel, Walter

doi:10.1002/(SICI)1521-3765(19990702)5:7<2101::AID-CHEM2101>3.0.CO;2-0

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Synthesis, Solid-State Structure, and Electronic Nature of a Phosphinine-Stabilized triangulo Palladium Cluster

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Reetz, Manfred T.
Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

Bohres, Edward
Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Goddard, Richard
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Reetz, M. T., Bohres, E., Goddard, R., Holthausen, M. C., & Thiel, W. (1999). Synthesis, Solid-State Structure, and Electronic Nature of a Phosphinine-Stabilized triangulo Palladium Cluster. Chemistry - A European Journal, 5(7), 2101-2108. doi:10.1002/(SICI)1521-3765(19990702)5:7<2101:AID-CHEM2101>3.0.CO;2-0.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-3AF5-1

Abstract

An unusual structure is found for a novel triangulo palladium cluster, stabilized by 2,4,6-triphenylphosphine and triethylphosphane (see figure; large open circles: Pd, small hashed circles: P, small open circles: C). The bonding involving phosphinine bridges between two Pd atoms is based on σ and π orbital interactions, as demonstrated by quantum-mechanical calculations of a model compound.