Transition Metal Complexes with the Proton Sponge 
4,9-Dichloroquino[7,8-h]quinoline: Highly Twisted Aromatic Systems and an 
Extreme “Out-of-Plane” Position of the Coordinated Transition Metal Atom

Wüstefeld, H. U.; Kaska, W.C.; Schüth, F.; Stucky, G.D.; Bu, X.; Krebs, B.

doi:10.1002/1521-3773(20010903)40:17<3182::AID-ANIE3182>3.0.CO;2-J

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Transition Metal Complexes with the Proton Sponge 4,9-Dichloroquino[7,8-h]quinoline: Highly Twisted Aromatic Systems and an Extreme “Out-of-Plane” Position of the Coordinated Transition Metal Atom

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Wüstefeld, H. U.
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Schüth, F.
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Wüstefeld, H. U., Kaska, W., Schüth, F., Stucky, G., Bu, X., & Krebs, B. (2001). Transition Metal Complexes with the Proton Sponge 4,9-Dichloroquino[7,8-h]quinoline: Highly Twisted Aromatic Systems and an Extreme “Out-of-Plane” Position of the Coordinated Transition Metal Atom. Angewandte Chemie International Edition, 40(17), 3182-3184. doi:10.1002/1521-3773(20010903)40:17<3182:AID-ANIE3182>3.0.CO;2-J.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0024-4605-B

Abstract

An extremely high thermal and chemical stability as well as a unique “out-of-plane” position of the metal atom is shown by the first stable transition metal complexes formed with the proton sponge 1 as the ligand. The properties of these complexes await wide application in catalysis and medicine.