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Journal Article

Eutectic Syntheses of Graphitic Carbon with High Pyrazinic Nitrogen Content

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Fechler,  Nina
Nina Fechler, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Rothe,  Regina
Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Schlögl,  Robert
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Willinger,  Marc Georg
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;
MPI for Chemical Energy Conversion;

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Antonietti,  Markus
Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Citation

Fechler, N., Zussblatt, N. P., Rothe, R., Schlögl, R., Willinger, M. G., Chmelka, B. F., et al. (2016). Eutectic Syntheses of Graphitic Carbon with High Pyrazinic Nitrogen Content. Advanced Materials, 28(6), 1287-1294. doi:10.1002/adma.201501503.


Cite as: https://hdl.handle.net/11858/00-001M-0000-0029-CF34-9
Abstract
Mixtures of phenols/ketones and urea show eutectic behavior upon gentle heating. These mixtures possess liquid-crystalline- like phases that can be processed. The architecture of phenol/ketone acts as structure-donating motif, while urea serves as melting-point reduction agent. Condensation at elevated temperatures results in nitrogen-containing carbons with remarkably high nitrogen content of mainly pyrazinic nature.