Generation of Nitrile N-Selenide (RCNSe) as Neutrals and Radical Cations in the Gas phase

[en] Cyanogen N-selenide radical cation, NCCNSe.+, is prepared by dissociative ionization of 3,4-dicyano-1,2,5-selenadiazole [1]. It reacts readily with nitriles in the gas phase to produce nitrile N-selenide ions, RCNSe.+. The stability of the corresponding n

Disciplines :

Chemistry

Author, co-author :

Gerbaux, Pascal

Flammang, Robert

Mørkved, Eva H.

Wong, Ming Wah

Wentrup, Curt

Language :

English

Title :

Generation of Nitrile N-Selenide (RCNSe) as Neutrals and Radical Cations in the Gas phase

Publication date :

01 January 1998

Journal title :

Tetrahedron Letters

ISSN :

0040-4039

Publisher :

Elsevier, United Kingdom

Volume :

Issue :

Pages :

533-536

Peer reviewed :

Peer Reviewed verified by ORBi

Research unit :

S836 - Synthèse et spectrométrie de masse organiques

Commentary :

Publié en ligne le 20 avril 1998 Lecture en ligne: http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6THS-3SH592F-7-3&_cdi=5290&_user=532054&_pii=S0040403997102283&_origin=search&_coverDate=02%2F12%2F1998&_sk=999609992&view=c&wchp=dGLbVzW-zSkzV&md5=dbf3050678c58f71ae204dec8dc94b21

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Bibliography

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15.The spectra were recorded on a large scale tandem mass spectrometer (Micromass AutoSpec 6F) (CS=charge stripping). For experimental details, see: Bateman, R.H.; Brown, J.; Lefevere, M.; Flammang, R.; Van Haverbeke, Y., Int.J. Mass Spectrom.Ion Processes, 1992, 115, 205-217.
16.The selanadiazole 1 was prepared according to the literature (Shew, D., Dis.Abs., 1959, 1593-1594) while 2 was prepared by reacting 1 with thiolacetic acid in benzene (experimental details will be reported in a full report).
17.Wiedman, F.A.; Cai, J.; Wesdemiotis, C., Rapid Commun.Mass Spectrom., 1994, 8, 804-807.
18.Flammang, R.; Van Haverbeke, Y.; Wong, M.W.; Wentrup, C., Rapid Commun.Mass Spectrom., 1995, 9, 203-208.
19.Flammang, R.; Barbieux-Flammang, M.; Gerbaux, P.; Wentrup, C.; Wong, M.W., Bull.Soc.Chim.Belg., 1997, 106, 000-000.
20.Computational details will be published separately: Wong, M.W.; Gerbaux, P.; Flammang, R.; Mørkved, E.H.; Wentrup, C., in preparation.
20.Flammang, R.; Van Haverbeke, Y.; Braybrook, C.; Brown, J., Rapid Commun.Mass Spectrom., 1995, 9, 795-799.