Materials Chemistry; Surfaces, Coatings and Films; Surfaces and Interfaces
Abstract :
[en] Electroless nickel-boron coatings were deposited from a novel deposition bath that was stabilizer-free. Those coatings were analyzed by DSC to determine the crystallization temperature of nickel-boride phases, and then the best heat treatment conditions for the new coatings were selected using the Knoop hardness test and XRD. The results of DSC analysis and XRD were coherent with the findings of previous studies, which shows that the new coating has a boron content lower than 4% wt. The maximum hardness was obtained after heat treatment at 300 °C for 4 h and reached 1196 ± 120 hk50, which is much higher than the as-deposited coating. The heat-treated coatings were then fully characterized using optical and scanning electron microscopy, as well tribological and corrosion tests. Various sliding tests (ball-on-disk and ball-on-flat configurations) were conducted to analyze the coefficient of friction (COF) and wear behavior of the coatings. The maximum von Mises stress was calculated, and values of 624 MPa and 728 MPa were obtained for the ball-on-disk and ball-on flat, respectively, at a depth close to 14 µm from the surface, confirming the suitability of the applied load. Abrasive, adhesive, and fatigue wear mechanisms were observed on the worn sample morphology using SEM. It has been determined that during the corrosion test the OCP and corrosion potential values for the heat-treated coating increase as compared with the as-deposited one, whereas its corrosion resistance decreases.
Research center :
CRIM - Ingénierie des matériaux
Disciplines :
Materials science & engineering
Author, co-author :
Vitry, Véronique ✱; Université de Mons - UMONS > Faculté Polytechnique > Service de Métallurgie
Mégret, Alexandre ; Université de Mons - UMONS > Faculté Polytechnique > Service de Métallurgie
Khalid, Hafiza Ayesha
Staia, Mariana Henriette
Montagne, Alex
Yunacti, Müslüm ✱; Université de Mons - UMONS > Faculté Polytechnique > Service de Métallurgie
✱ These authors have contributed equally to this work.
Language :
English
Title :
Selection of New Heat Treatment Conditions for Novel Electroless Nickel-Boron Deposits and Characterization of Heat-Treated Coatings
Shakoor R.A. Kahraman R. Gao W. Wang Y. Synthesis, Characterization and Applications of Electroless Ni-B Coatings—A Review Int. J. Electrochem. Sci. 2016 11 2486 2512
Anik M. Körpe E. Şen E. Effect of Coating Bath Composition on the Properties of Electroless Nickel-Boron Films Surf. Coat. Technol. 2008 202 1718 1727 10.1016/j.surfcoat.2007.07.031
Oriňáková R. Oriňák A. Kupková M. Sabalová M. Fedorková A.S. Kabátová M. Kal’avskỳ F. Sedlaříková M. Effect of Heat Treatment on the Corrosion and Mechanical Properties of Electrolytical Composite Ni-B Coatings Int. J. Electrochem. Sci. 2014 9 4268 4286
Sudagar J. Lian J. Sha W. Electroless Nickel, Alloy, Composite and Nano Coatings—A Critical Review J. Alloys Compd. 2013 571 183 204 10.1016/j.jallcom.2013.03.107
Madah F. Dehghanian C. Amadeh A.A. Investigations on the Wear Mechanisms of Electroless Ni-B Coating during Dry Sliding and Endurance Life of the Worn Surfaces Surf. Coat. Technol. 2015 282 6 15 10.1016/j.surfcoat.2015.09.003
García-Aguirre C.A. Domínguez-Ríos C. Torres-Sánchez R. Román-Aguirre M. Holguín-Momaca J.T. Aguilar-Elguézabal A. Microstructure and Transmission Electron Microscopy Characterization of Electroless Ni-B Thin Films Deposited on MWCNTs Surf. Coat. Technol. 2015 282 107 114 10.1016/j.surfcoat.2015.10.023
Vitry V. Hastir J. Mégret A. Yazdani S. Yunacti M. Bonin L. Recent Advances in Electroless Nickel-boron Coatings Surf. Coat. Technol. 2022 429 127937 10.1016/j.surfcoat.2021.127937
Schlesinger M. Electroless Deposition of Nickel Modern Electroplating 5th ed. John Wiley & Sons, Inc. Hoboken, NJ, USA 2011 4 447 458 10.1002/9780470602638.ch18
Barati Q. Hadavi S.M.M. Electroless Ni-B and Composite Coatings: A Critical Review on Formation Mechanism, Properties, Applications and Future Trends Surf. Interfaces 2020 21 100702 10.1016/j.surfin.2020.100702
Narayanan T.S.N.S. Krishnaveni K. Seshadri S.K. Electroless Ni-P/Ni-B Duplex Coatings: Preparation and Evaluation of Microhardness, Wear and Corrosion Resistance Mater. Chem. Phys. 2003 82 771 779 10.1016/S0254-0584(03)00390-0
Krishnaveni K. Sankara Narayanan T.S.N. Seshadri S.K. Electroless Ni-B Coatings: Preparation and Evaluation of Hardness and Wear Resistance Surf. Coat. Technol. 2005 190 115 121 10.1016/j.surfcoat.2004.01.038
Kanta A.F. Vitry V. Delaunois F. Wear and Corrosion Resistance Behaviours of Autocatalytic Electroless Plating J. Alloys Compd. 2009 486 21 23 10.1016/j.jallcom.2009.07.038
Mukhopadhyay A. Barman T.K. Sahoo P. Effect of Heat Treatment on the Characteristics of Electroless Ni-B, Ni-B-W and Ni-B-Mo Coatings Mater. Today Proc. 2018 5 3306 3315 10.1016/j.matpr.2017.11.573
Georgiza E. Gouda V. Vassiliou P. Production and Properties of Composite Electroless Ni-B-SiC Coatings Surf. Coat. Technol. 2017 325 46 51 10.1016/j.surfcoat.2017.06.019
Delaunois F. Lienard P. Heat Treatments for Electroless Nickel-Boron Plating on Aluminium Alloys Surf. Coat. Technol. 2002 160 239 248 10.1016/S0257-8972(02)00415-2
Vitry V. Bonin L. Increase of Boron Content in Electroless Nickel-Boron Coating by Modification of Plating Conditions Surf. Coat. Technol. 2017 311 164 171 10.1016/j.surfcoat.2017.01.009
Gilley K.L. Nino J.C. Riddle Y.W. Hahn D.W. Perry S.S. Heat Treatments Modify the Tribological Properties of Nickel Boron Coatings ACS Appl. Mater. Interfaces 2012 4 3069 3076 10.1021/am3004297
Wan Y. Yu Y. Cao L. Zhang M. Gao J. Qi C. Corrosion and Tribological Performance of PTFE-Coated Electroless Nickel Boron Coatings Surf. Coat. Technol. 2016 307 316 323 10.1016/j.surfcoat.2016.09.001
Tima R. Mahboubi F. Effect of Plasma Nitriding Temperature on Microstructure and Wear Properties of Electroless Nickel-Boron Coatings Surf. Coat. Technol. 2021 415 127084 10.1016/j.surfcoat.2021.127084
Zhang J. Xie Z.H. Chen H. Hu C. Li L. Hu B. Song Z. Yan D. Yu G. Electroless Deposition and Characterization of a Double-Layered Ni-B/Ni-P Coating on AZ91D Mg Alloy from Eco-Friendly Fluoride-Free Baths Surf. Coat. Technol. 2018 342 178 189 10.1016/j.surfcoat.2018.02.105
Niksefat V. Ghorbani M. Mechanical and Electrochemical Properties of Ultrasonic-Assisted Electroless Deposition of Ni-B-TiO2 Composite Coatings J. Alloys Compd. 2015 633 127 136 10.1016/j.jallcom.2015.01.250
Domínguez-Ríos C. Hurtado-Macias A. Torres-Sánchez R. Ramos M.A. González-Hernández J. Measurement of Mechanical Properties of an Electroless Ni-B Coating Using Nanoindentation Ind. Eng. Chem. Res. 2012 51 7762 7768 10.1021/ie201760g
Qian W. Wei H. Chen H. Zhu L. Sun Y. Han S. Lin H. Jiang J. The Effect of Heat Treatment on Ni–B–Ce Electroless Coatings Surf. Eng. 2019 35 145 153 10.1080/02670844.2018.1442697
Bülbül F. Altun H. Küçük Ö. Ezirmik V. Tribological and Corrosion Behaviour of Electroless Ni-B Coating Possessing a Blackberry like Structure Met. Mater. Int. 2012 18 631 637 10.1007/s12540-012-4011-1
Bonin L. Vitry V. Delaunois F. Corrosion Behaviour of Electroless High Boron-Mid Phosphorous Nickel Duplex Coatings in the as-Plated and Heat-Treated States in NaCl, H2SO4, NaOH and Na2SO4 Media Mater. Chem. Phys. 2018 208 77 84 10.1016/j.matchemphys.2017.12.030
Keong K.G. Sha W. Malinov S. Hardness Evolution of Electroless Nickel-Phosphorus Deposits with Thermal Processing Surf. Coat. Technol. 2003 168 263 274 10.1016/S0257-8972(03)00209-3
Biswas A. Das S.K. Sahoo P. Correlating Tribological Performance with Phase Transformation Behavior for Electroless Ni-(High)P Coating Surf. Coat. Technol. 2017 328 102 114 10.1016/j.surfcoat.2017.08.043
Vitry V. Delaunois F. Dumortier C. Mechanical Properties and Scratch Test Resistance of Nickel-Boron Coated Aluminium Alloy after Heat Treatments Surf. Coat. Technol. 2008 202 3316 3324 10.1016/j.surfcoat.2007.12.001
Vitry V. Delaunois F. Dumortier C. How Heat Treatment Can Give Better Properties to Electroless Nickel-Boron Coatings Metall. Ital. 2009 101 1 6
Vitry V. Electroless Nickel-Boron Deposits: Synthesis, Formation and Characterization; Effect of Heat Treatments; Analytical Modeling of the Structural State Ph.D. Thesis University of Mons Mons, Belgium 2009
Ghavidel N. Allahkaram S.R. Naderi R. Barzegar M. Bakhshandeh H. Corrosion and Wear Behavior of an Electroless Ni-P/Nano-SiC Coating on AZ31 Mg Alloy Obtained through Environmentally-Friendly Conversion Coating Surf. Coat. Technol. 2020 382 125156 10.1016/j.surfcoat.2019.125156
Pal S. Verma N. Jayaram V. Biswas S.K. Riddle Y. Characterization of Phase Transformation Behaviour and Microstructural Development of Electroless Ni-B Coating Mater. Sci. Eng. A 2011 528 8269 8276 10.1016/j.msea.2011.07.060
Bonin L. Vitry V. Delaunois F. Replacement of Lead Stabilizer in Electroless Nickel-Boron Baths: Synthesis and Characterization of Coatings from Bismuth Stabilized Bath Sustain. Mater. Technol. 2020 23 e00130 10.1016/j.susmat.2019.e00130
Bonin L. Vitry V. Delaunois F. The Tin Stabilization Effect on the Microstructure, Corrosion and Wear Resistance of Electroless NiB Coatings Surf. Coat. Technol. 2019 357 353 363 10.1016/j.surfcoat.2018.10.011
Yunacti M. Mégret A. Staia M.H. Montagne A. Vitry V. Characterization of Electroless Nickel–Boron Deposit from Optimized Stabilizer-Free Bath Coatings 2021 11 576 10.3390/coatings11050576
Bonin L. Castro C.C. Vitry V. Hantson A.L. Delaunois F. Optimization of Electroless NiB Deposition without Stabilizer, Based on Surface Roughness and Plating Rate J. Alloys Compd. 2018 767 276 284 10.1016/j.jallcom.2018.06.330
Oliver W.C. Pharr G.M. An Improved Technique for Determining Hardness and Elastic Modulus Using Load and Displacement Sensing Indentation Experiments J. Mater. Res. 1992 7 1564 1583 10.1557/JMR.1992.1564
Sankara Narayanan T.S.N. Seshadri S.K. Formation and Characterization of Borohydride Reduced Electroless Nickel Deposits J. Alloys Compd. 2004 365 197 205 10.1016/S0925-8388(03)00680-7
Matik U. The Influence of Heat-Treatment on Hardness and Structural Characteristics of Electroless Ni-B Deposited Ferrous Powder Metal Compacts Gazi Üniv. Fen Bilim. Derg. Part C Tasar. Teknol. 2017 5 223 230
Balaraju J.N. Priyadarshi A. Kumar V. Manikandanath N.T. Kumar P.P. Ravisankar B. Hardness and Wear Behaviour of Electroless Ni–B Coatings Mater. Sci. Technol. 2016 32 1654 1665 10.1080/02670836.2015.1137683
Serin I.G. Göksenli A. Effect of Annealing Temperature on Hardness and Wear Resistance of Electroless Ni-B-Mo Coatings Surf. Rev. Lett. 2015 22 1550058 10.1142/S0218625X15500584
Vitry V. Kanta A.F. Dille J. Delaunois F. Structural State of Electroless Nickel-Boron Deposits (5wt. % B): Characterization by XRD and TEM Surf. Coat. Technol. 2012 206 3444 3449 10.1016/j.surfcoat.2012.02.003
Okamoto H. Schlesinger M. Mueller E. B (Boron) Binary Alloy Phase Diagrams Alloy Phase Diagrams ASM International Almere, The Netherlands 2018 13 174 184 10.31399/asm.hb.v03.a0006147
Delaunois F. Vitry V. Bonin L. Electroless Nickel Plating, Fundamentals to Applications Taylor & Francis Group Croydon, UK 2019 13:978-1-138-60580-0
Oraon B. Majumdar G. Ghosh B. Improving Hardness of Electroless Ni-B Coatings Using Optimized Deposition Conditions and Annealing Mater. Des. 2008 29 1412 1418 10.1016/j.matdes.2007.09.005
Vitry V. Delaunois F. Nanostructured Electroless Nickel-Boron Coatings for Wear Resistance Elsevier Ltd. Amsterdam, The Netherlands 2014 9780857092175
Montagne A. Vitry V. Bonin L. Mughal M.Z. Sebastiani M. Iost A. Staia H. Contraintes Résiduelles et Comportement Mécanique de Revêtements Nickel-Bore Matér. Tech. 2019 107 205 10.1051/mattech/2019016
Finch C.B. Cavin O.B. Becher P.F. Crystal Growth and Properties of Trinickel Boride, Ni3B J. Cryst. Growth 1984 67 556 558 10.1016/0022-0248(84)90050-2
Arias S. Castaño J.G. Correa E. Echeverría F. Gómez M. Effect of Heat Treatment on Tribological Properties of Ni-B Coatings on Low Carbon Steel: Wear Maps and Wear Mechanisms J. Tribol. 2019 141 091601 10.1115/1.4043906
Balaraju J.N. Selvi V.E. Grips V.K.W. Rajam K.S. Electrochemical Studies on Electroless Ternary and Quaternary Ni-P Based Alloys Electrochim. Acta 2006 52 1064 1074 10.1016/j.electacta.2006.07.001
Das S.K. Sahoo P. Electrochemical Impedance Spectroscopy of Ni-B Coatings and Optimization by Taguchi Method and Grey Relational Analysis Port. Electrochim. Acta 2011 29 211 231 10.4152/pea.201104211
Anık M. Körpe E. Baksan B. Isıl Işlemin Akımsız Ni.B Kaplamanın Mikro-Yapısına, Korozyon Direncine ve Sertliğine Etkisi Eskişeh. Osmangazi Üniv. Mühendis. Mimar. Fak. Derg. 2009 22 111 124
Vitry V. Sens A. Kanta A.F. Delaunois F. Wear and Corrosion Resistance of Heat Treated and As-Plated Duplex NiP/NiB Coatings on 2024 Aluminum Alloys Surf. Coat. Technol. 2012 206 3421 3427 10.1016/j.surfcoat.2012.01.049