[en] The self-assembly of a series of tetrathiafulvalene (TTF) derivatives at the interface between non-volatile organic solutions and the graphite surface has been studied by scanning tunnelling microscopy (STM). The TTFs have been prepared such that they bear none, one, two (in different constitutions) or four alkyl chains of different lengths and different functional groups. The STM images reveal that the packing of the TTF cores can effectively be controlled by changing the substitution pattern on the heterocycle. Several structures are seen at the interphase-parquet-type packing, single and double core tapes, and even isolated molecules-all of which have the TTF core essentially coplanar with the surface. Molecular modelling has shown that several orientations of the molecules are practically equal in energy on the graphite, which explains the polymorphous packing of some of the molecules. Solvent effects also play a role in determining the 2D structures.
Disciplines :
Chemistry
Author, co-author :
Abdel-Mottaleb, M.M.S.
Gomar-Nadal, E.
Surin, Mathieu ; Université de Mons > Faculté des Sciences > Chimie des matériaux nouveaux
Uji-I, I.
Mamdouh, W.
Veciana, J.
Lemaur, Vincent ; Université de Mons > Faculté des Sciences > Chimie des matériaux nouveaux
Self-Assembly of Tetrathiafulvalene Derivatives at a Liquid-Solid Interface: Compositional and Constitutional Influence on Supramolecular Ordering
Publication date :
21 November 2005
Journal title :
Journal of Materials Chemistry B
ISSN :
2050-750X
eISSN :
2050-7518
Publisher :
Royal Society of Chemistry, United Kingdom
Volume :
15
Issue :
43
Pages :
4601-4615
Peer reviewed :
Peer Reviewed verified by ORBi
Research unit :
S817 - Chimie des matériaux nouveaux
Research institute :
R400 - Institut de Recherche en Science et Ingénierie des Matériaux
Commentary :
Publié en ligne le 26 septembre 2005
Lecture en ligne: http://www.rsc.org/delivery/_ArticleLinking/DisplayArticleForFree.cfm?doi=b509336h&JournalCode=JM
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