Stereocomplexed materials based on poly(3-hexylthiophene)-b-poly(lactide) block copolymers : synthesis by organic catalysis, thermal properties and microscopic morphology

Grancharov, Georgy; Coulembier, Olivier; Surin, Mathieu; Lazzaroni, Roberto; Dubois, Philippe

doi:10.1021/ma1012336

Article (Scientific journals)

Stereocomplexed materials based on poly(3-hexylthiophene)-b-poly(lactide) block copolymers : synthesis by organic catalysis, thermal properties and microscopic morphology

Grancharov, Georgy; Coulembier, Olivier; Surin, Mathieu et al.

2010 • In Macromolecules, 43 (21), p. 8957-8964

Peer Reviewed verified by ORBi

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https://hdl.handle.net/20.500.12907/964

DOI
10.1021/ma1012336

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Abstract :

[en] A new approach to control the supramolecular organization of conjugated polymers is proposed, based on stereocomplex formation. It is illustrated by mixing polymer solutions of block copolymers, i.e., poly(3-hexylthiophene)-b-poly(l-lactide) and poly(3-hexylthiophene)-b-poly(d-lactide). The block copolymers were successfully synthesized via a three-step procedure including the use of metal-free organic catalysts in the ring-opening polymerization of l- and d-lactide. The thermal properties and microscopic morphology of sterecomplexed diblock copolymers show that the stereocomplexation of the polylactide blocks is able to prevent the crystallization of the regioregular poly(3-hexylthiophene) block into long-range ordered parallel fibrillar structures. Stereocomplexation is also observed when mixing poly(d-lactide) homopolymer and poly(3-hexylthiophene)-b-poly(l-lactide) block copolymer.

Disciplines :

Chemistry

Author, co-author :

Grancharov, Georgy

Coulembier, Olivier ; Université de Mons > Faculté des Sciences > Matériaux Polymères et Composites

Surin, Mathieu ; Université de Mons > Faculté des Sciences > Service de Chimie des matériaux nouveaux

Lazzaroni, Roberto ; Université de Mons > Faculté des Sciences > Service de Chimie des matériaux nouveaux

Dubois, Philippe ; Université de Mons > Faculté des Sciences > Matériaux Polymères et Composites

Language :

English

Title :

Stereocomplexed materials based on poly(3-hexylthiophene)-b-poly(lactide) block copolymers : synthesis by organic catalysis, thermal properties and microscopic morphology

Publication date :

15 October 2010

Journal title :

Macromolecules

ISSN :

0024-9297

Publisher :

American Chemical Society (ACS), United States - District of Columbia

Volume :

Issue :

Pages :

8957-8964

Peer reviewed :

Peer Reviewed verified by ORBi

Research unit :

S816 - Matériaux Polymères et Composites
S817 - Chimie des matériaux nouveaux

Research institute :

R400 - Institut de Recherche en Science et Ingénierie des Matériaux

Commentary :

Publiée en ligne le 13 octobre 2010

Available on ORBi UMONS :

since 25 January 2011

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