Restrepo Gutiérrez, Oscar Antonio
[UCL]
(eng)
Using molecular dynamics simulations, the present research has been
focused on the elucidation of the mechanisms of sputtering of hybrid
metal-organic surfaces. This study takes place in the context of surface
analysis by secondary ion mass spectrometry, a method in which
kiloelectronvolt projectiles are used to bombard the samples and the ions
emitted by the surface are mass-analyzed. The central question here
was to understand the beneficial effect of the presence of gold
nanoparticles (NPs) in organic surfaces for molecular and fragment ion
emission enhancement, experimentally observed when atomic projectiles
were used, and why a different behavior occurred upon polyatomic
projectile bombardment. In the process of answering this question, some
of the most fundamental aspects involved in the keV bombardment, by
monoatomic and polyatomic projectiles (Ga, C60, Aun and Arn), of a
polymeric solid covered by gold NPs as well as of the interface between a
gold crystal and a polymer, have been unveiled. Special attention was
given to the influence of the metal in the energy deposition process and in
the formation of the sputtered organic species. Two important results of
this research, valid for atoms and clusters, are that (1) the sputter yield is
proportional to the quantity of energy deposited in the extreme surface of
the polymer, which depends directly on the stopping power and inversely
on the range of the projectile, and (2) the sputtering maximizes when the
atomic masses of the cluster projectile and target match, i.e. when the
energy transfer and the angular dispersion in diatomic collisions are
maximum. In addition, the detailed analysis of the simulations provides
abundant information concerning, e.g., the projectile implantation,
damage produced in the target, induced pressure waves, crater sizes,
and mass, energy and origin of the emitted fragments, as a function of the
initial conditions, which should be useful for experimentalists.
Bibliographic reference |
Restrepo Gutiérrez, Oscar Antonio. Molecular dynamics study of the sputtering of nanostructured metal-organic surfaces. Prom. : Delcorte, Arnaud |
Permanent URL |
http://hdl.handle.net/2078.1/111850 |