Magnetic Study of a Layered Lanthanide Hydroxide family: Ln8(OH)20Cl4·nH2O (Ln 
= Tb, Ho, Er)

Coutinho, J. T.; Pereira, C. C. L.; Marçalo, J.; Baldovi, J.; Almeida, M.; Monteiro, B.; Pereira, L. C. J.

doi:10.1039/C8DT03672A

アイテム詳細

登録内容を編集ファイル形式で保存

一時保存へ追加

このアイテムの新しいバージョンが利用可能です:
https://pure.mpg.de/pubman/item/item_3005554_8

詳細要約

公開

学術論文

Magnetic Study of a Layered Lanthanide Hydroxide family: Ln₈(OH)₂₀Cl₄·nH₂O (Ln = Tb, Ho, Er)

MPS-Authors

/persons/resource/persons214173

Baldovi, J.
Theory Group, Theory Department, Max Planck Institute for the Structure and Dynamics of Matter, Max Planck Society;

External Resource

https://dx.doi.org/10.1039/C8DT03672A
(出版社版)

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

フルテキスト (公開)

c8dt03672a.pdf
(ポストプリント), 2MB

付随資料 (公開)

c8dt03672a1.pdf
(付録資料), 4MB

引用

Coutinho, J. T., Pereira, C. C. L., Marçalo, J., Baldovi, J., Almeida, M., Monteiro, B., & Pereira, L. C. J. (2018). Magnetic Study of a Layered Lanthanide Hydroxide family: Ln₈(OH)₂₀Cl₄·nH₂O (Ln = Tb, Ho, Er). Dalton Transactions, 47(45), 16211-16217. doi:10.1039/C8DT03672A.

引用: https://hdl.handle.net/21.11116/0000-0002-5FDB-E

要旨

Three layered lanthanide hydroxides (LLHs), with the general formula Ln8(OH)20Cl4·nH2O (Ln = Tb (1), Ho (2), Er (3)), were prepared and magnetically characterized. These compounds were further diluted within a yttrium diamagnetic matrix, LYH:xLn, LYH:0.044Tb (1’), LYH:0.045Ho (2’), and LYH:0.065Er (3’), being the study complemented with theoretical calculations in order to understand the electronic configuration and the contributions to the slow relaxation behavior. In the pure compounds dominant 3D ferromagnetic interactions are observed, with a small magnetization hysteresis at 1.8 K for 1, while the magnetically diluted solid solutions display slow relaxation of the magnetization at low temperatures.