Study Concerning the Effects of Chelation on the Structure and Catalytic 
Activity of Ruthenium Carbene Complexes

Fürstner, Alois; Thiel, Oliver R.; Lehmann, Christian W.

doi:10.1021/om0108503

Item

ITEM ACTIONSEXPORT

Add to Basket

Local TagsRelease HistoryDetailsSummary

Released

Journal Article

Study Concerning the Effects of Chelation on the Structure and Catalytic Activity of Ruthenium Carbene Complexes

MPS-Authors

/persons/resource/persons58380

Fürstner, Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons135965

Thiel, Oliver R.
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58744

Lehmann, Christian W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Resource

No external resources are shared

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

Fulltext (public)

There are no public fulltexts stored in PuRe

Supplementary Material (public)

There is no public supplementary material available

Citation

Fürstner, A., Thiel, O. R., & Lehmann, C. W. (2002). Study Concerning the Effects of Chelation on the Structure and Catalytic Activity of Ruthenium Carbene Complexes. Organometallics, 21(2), 331-335. doi:10.1021/om0108503.

Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-9A29-8

Abstract

The ruthenium chelate complexes 4 and 5 were prepared by reaction of the Grubbs catalyst 1 and its second-generation analogue 2 with the 2-vinylbenzoic acid isopropyl ester 3 in the presence of CuCl. The fact that the chelating carbonyl group in these complexes attenuates their catalytic activity sets an experimental basis for the interpretation of reactivity data previously described in the literature.