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Journal Article

Rotating Chemical Waves in Small Circular Domains

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Hartmann,  Nils Olaf
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

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Bär,  Markus
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

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Krischer,  Katharina
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

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PhysRevLett.76.1384.pdf
(Publisher version), 143KB

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Citation

Hartmann, N. O., Bär, M., Kevrekidis, I. G., Krischer, K., & Imbihl, R. (1996). Rotating Chemical Waves in Small Circular Domains. Physical Review Letters, 76(8), 1384-1387. doi:10.1103/PhysRevLett.76.1384.


Cite as: https://hdl.handle.net/21.11116/0000-0009-AFC7-2
Abstract
The influence of the domain size on the properties of rotating waves in the NO+CO reaction on a microstructured Pt(100) surface is investigated for circular geometries. Below a critical domain size, determined by the spiral wavelength in an unbounded medium, the frequency of the rotating waves increases substantially due to interaction of the wave tip with the boundary. The phenomena are reproduced qualitatively with a reaction-diffusion model.