Infrared resonance enhanced multi-photon ionization spectroscopy of C84

von Helden, G.; Holleman, I.; Putter, M.; van Roij, A.J.A.; Meijer, Gerard

doi:10.1016/S0009-2614(98)01259-7

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Infrared resonance enhanced multi-photon ionization spectroscopy of C₈₄

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Citation

von Helden, G., Holleman, I., Putter, M., van Roij, A., & Meijer, G. (1999). Infrared resonance enhanced multi-photon ionization spectroscopy of C₈₄. Chemical Physics Letters, 299(2), 171-176. doi:10.1016/S0009-2614(98)01259-7.

Cite as: https://hdl.handle.net/21.11116/0000-000B-6432-C

Abstract

Gas-phase C₈₄ is resonantly excited using infrared (IR) radiation from a free electron laser. At specific wavelengths, strong ion signals are observed, resulting from thermionic emission of electrons by the fullerenes. The mass-selected ion yield is recorded as a function of IR frequency and the resulting spectrum yields information on the electronic ground state of the gas-phase molecule.