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要旨

The room-temperature face-centered cubic (FCC-a₀) phase as well as the low-temperature simple cubic (SC) phase of C₆₀ are studied by electron microscopy and electron diffraction. The micro-structure of the room-temperature FCC-a₀ phase is very similar to that of a low stacking fault energy FCC alloy; micro twins and stacking faults on the {111} planes are the main defects. High-resolution observations of these defects are presented here. In some parts the high-resolution images suggest a reconstructed lattice at the surface, possibly due to the presence of oxygen. The phase transition FCC-a₀ ⇒ simple cubic (SC) at 255 K is confirmed and the observed reflections in the SC phase are only compatible with the space group Pa3. A second phase transition SC ⇒ FCC-2a₀ is reported. It occurs presumably at a slightly lower temperature. It is suggested that in the SC phase the molecules still have some rotational degree of freedom about their respective 〈111〉 rotation axis. In the FCC-2a₀ phase the rotation angle is assumed to be frozen in and to alternate between + ϕ and - ϕ along the 〈100〉 directions.
C₇₀ can grow either hexagonally close-packed (HCP) or cubic close-packed (FCC). On cooling the HCP crystals undergo a phase transformation whereby the c / a ratio increases from 1.64 to 1.82. At lower temperatures the C₇₀ molecules orient themselves inside the close-packed planes to induce a monoclinic C-centered superstructure. Above room temperature a shear transformation from ABAB… to ABCABC… occurs. Due to the ellipsoidal shape of the molecule, however, the structure is only rhombohedral with α = 88°-89°. Only at higher temperatures does the structure gradually become FCC.