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Vacancy-enhanced oxygen redox and structural stability of spinel Li2Mn3O7-x

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Hu,  Zhiwei
Zhiwei Hu, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Citation

Yang, L., Liu, Z., Li, S., Hu, Z., Kong, Q., Shen, X., et al. (2022). Vacancy-enhanced oxygen redox and structural stability of spinel Li2Mn3O7-x. Chemical Communications, 58, 11685-11688. doi:10.1039/d2cc03259g.


Cite as: https://hdl.handle.net/21.11116/0000-000B-44B4-D
Abstract
Vacancies have been proved effective in activating the oxygen redox and stabilizing the structure of the oxide cathode materials for the Na-ion batteries, but their effect on the cathode materials of the Li-ion batteries is unclear. We herein show that they have similar effect on spinel [Li4/7Mn2/71/7](8a)[Li4/7Mn10/7](16d)[O4-x '](32e).