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Practical Aspects of Thermal Dissociation and Recombination Reactions: the Reaction Systems CF3X(+M)<-> CF3+X (+M) with X=F, Cl, Br, and I

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Tellbach,  Elsa
Emeritus Group Spectroscopy and Photochemical Kinetics, Max Planck Institute for Multidisciplinary Sciences, Max Planck Society;

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Sölter,  Lars
Emeritus Group Spectroscopy and Photochemical Kinetics, Max Planck Institute for Multidisciplinary Sciences, Max Planck Society;

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Troe,  Jürgen
Emeritus Group Spectroscopy and Photochemical Kinetics, Max Planck Institute for Multidisciplinary Sciences, Max Planck Society;

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Citation

Cobos, C. J., Tellbach, E., Sölter, L., & Troe, J. (2023). Practical Aspects of Thermal Dissociation and Recombination Reactions: the Reaction Systems CF3X(+M)<-> CF3+X (+M) with X=F, Cl, Br, and I. Israel Journal of Chemistry, in press. doi:10.1002/ijch.202300006.


Cite as: https://hdl.handle.net/21.11116/0000-000C-F5EE-4
Abstract
The thermal dissociation/recombination reactions of the perfluoromethyl halides CF4↔CF3+F, CF3Cl↔CF3+Cl, CF3Br↔CF3+Br, and CF3I↔CF3+I are analyzed with respect to their transition (for increasing pressures) from second-order to first-order dissociation (or from third-order to second-order recombination). The dependence of this transition on the temperature is documented. Practical aspects of the modelling of falloff curves are discussed.