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Studies in aryne chemistry

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thesis
posted on 2018-09-19, 14:54 authored by John M. Jablonski
The principal methods for the generation of arynes and the types of reactions which they undergo are briefly reviewed. Tetrachlorobenzyne has been generated from pentachlorophenyl magnesium chloride, pentachlorophenyl lithium, and tetrachloroanthranilic acid. Reactions of tetrachlorobenzyne with benzene, substituted benzenes, naphthalene, anthracene, furan, tetraphenylcyclopentadienone, 1,3-diphenyl-isobenzofuran, crotonaldehyde and acrolein are reported. Cycloadducts are obtained from those reactions in good yield. Certain reactions of tetrachlor-4-pyridyl lithium are reported. [Continues.]

Funding

Loughborough University of Technology (research studentship).

History

School

  • Science

Department

  • Chemistry

Publisher

© John M. Jablonski

Publisher statement

This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/

Publication date

1968

Notes

A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.

Language

  • en

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    Chemistry Theses

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    untaggedChemical Sciences not elsewhere classified

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    CC BY-NC-ND 4.0

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